Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Nitration of Phenacetin
#### 1. Arrange the following in the order of reactivity to electrophilic aromatic substitution reactions and explain.
(i)
(a) Ph-Cl \
(b) \[ \text{Ph-CHO} \] \
(c) \[ \text{Ph-OCH}_3 \] \
(d) \[ \text{Ph-N(CH}_3\text{)_3}^+ \]
(ii)
(a) \[ \text{Ph-NHCOCH}_3 \] \
(b) \[ \text{Ph-N==CH}_2 \] \
(c) \[ \text{Ph-COPh} \] \
(d) \[ \text{Ph-SMe} \]
#### 2. Predict the products and explain.
(i) \[
\begin{array}{c}
\begin{tikzpicture}
\draw (0,0) -- (1,0.6);
\draw (1,0.6) -- (2,0);
\draw (2,0) -- (2,-1);
\draw (2,-1) -- (1,-1.6);
\draw (1,-1.6) -- (0,-1);
\draw (0,-1) -- (0,0);
\draw (0.7,0.3) -- (0.7,-0.7);
\draw (1.3,0.3) -- (1.3,-0.7);
\draw (0.7,0.3) -- (-0.5,0.3);
\draw (-0.5,0.3) -- (-0.7,0.5);
\draw (-0.5,0.1) -- (-0.5,0.6);
\draw (1.3,0.3) -- (0.7,1.2);
\draw (1.5,1.3) -- (2,1.6);
\node at (3,0.3) {Br};
\end{tikzpicture}
\]
Nitration →
(ii) \[
\begin{array}{c}
\begin{tikzpicture}
\draw (0,0) -- (1,0.6);
\draw (1,0.6) -- (2,0);
\draw (2,0) -- (2,-1](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2405e5cb-20d1-4277-a72a-e2ca429d5d5b%2F68149fa6-c5e4-4112-b8d7-4bc9e4a6f86a%2Fb95snd1_processed.png&w=3840&q=75)
Transcribed Image Text:### Nitration of Phenacetin
#### 1. Arrange the following in the order of reactivity to electrophilic aromatic substitution reactions and explain.
(i)
(a) Ph-Cl \
(b) \[ \text{Ph-CHO} \] \
(c) \[ \text{Ph-OCH}_3 \] \
(d) \[ \text{Ph-N(CH}_3\text{)_3}^+ \]
(ii)
(a) \[ \text{Ph-NHCOCH}_3 \] \
(b) \[ \text{Ph-N==CH}_2 \] \
(c) \[ \text{Ph-COPh} \] \
(d) \[ \text{Ph-SMe} \]
#### 2. Predict the products and explain.
(i) \[
\begin{array}{c}
\begin{tikzpicture}
\draw (0,0) -- (1,0.6);
\draw (1,0.6) -- (2,0);
\draw (2,0) -- (2,-1);
\draw (2,-1) -- (1,-1.6);
\draw (1,-1.6) -- (0,-1);
\draw (0,-1) -- (0,0);
\draw (0.7,0.3) -- (0.7,-0.7);
\draw (1.3,0.3) -- (1.3,-0.7);
\draw (0.7,0.3) -- (-0.5,0.3);
\draw (-0.5,0.3) -- (-0.7,0.5);
\draw (-0.5,0.1) -- (-0.5,0.6);
\draw (1.3,0.3) -- (0.7,1.2);
\draw (1.5,1.3) -- (2,1.6);
\node at (3,0.3) {Br};
\end{tikzpicture}
\]
Nitration →
(ii) \[
\begin{array}{c}
\begin{tikzpicture}
\draw (0,0) -- (1,0.6);
\draw (1,0.6) -- (2,0);
\draw (2,0) -- (2,-1
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