are intermediate in length as is common in aromatics, the C-B bonds are very long - they are the length of Boron heterocyclics are similar if opposite: the boron can use either a singly occupied or empty orbital as part of they are extremely strong Lewis Some interesting bora-aromatics have been made as shown below. In these compounds, while the C-Cbonds Acids, and are only known as complexes. Boron can also use an empty orbital in the pi system: borepins are the pi system: pyridine and pyrrole. The convention is that lone pairs inside the ring are part of the pi sstem, 4. Nitrogen containing heterocyclic aromatics can use either a singly occupied orbital or the lone pair as part of JAMES E. HANSON lone pairs outside are not. Work The The рyridine ругrole 1. the pi system! Boratobenzenes have a boron replacing a carbon in benzene - isoelectronic with the cycloheptatrienyl cation. a boratobenzene borepin typical single bonds. Why?

are intermediate in length as is common in aromatics, the C-B bonds are very long - they are the length of Boron heterocyclics are similar if opposite: the boron can use either a singly occupied or empty orbital as part of they are extremely strong Lewis Some interesting bora-aromatics have been made as shown below. In these compounds, while the C-Cbonds Acids, and are only known as complexes. Boron can also use an empty orbital in the pi system: borepins are the pi system: pyridine and pyrrole. The convention is that lone pairs inside the ring are part of the pi sstem, 4. Nitrogen containing heterocyclic aromatics can use either a singly occupied orbital or the lone pair as part of JAMES E. HANSON lone pairs outside are not. Work The The рyridine ругrole 1. the pi system! Boratobenzenes have a boron replacing a carbon in benzene - isoelectronic with the cycloheptatrienyl cation. a boratobenzene borepin typical single bonds. Why?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Thoroughly describe what is meant when a compound is considered aromatic. In your answer, provide examples and be sure to discuss how Huckel's Rule applies, and what it means to be anti-aromatic versus non-aromatic. When providing specific examples to demonstrate the requirements that you list, describe the delocalized pi electrons and sp2 hybridization. Lastly, why is benzene so special compared to alkenes like cyclohexene....both are 6-carbon atom cycles so are they chemically similar or not really similar at all?
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