f(o)= KBT Vc 1 |--ømø + (1 − 6) ln(1 − 6) + x6(1 − ø) N Π II = kBT [ф Vc N X In(1 - 6) - 6- x6² - to:²] = 1 1 + 21 6 No (2.62) (2.66) (3) Following Sec. 2.4.1, using the (mean-field) Flory-Huggin free energy of mixing for a polymer solution (Eq. (2.62)), derive Eq. (2.63) and hence the van't Hoff's law. Show that the coexistence curve is given by (2.66) and compute the critical point. (2.63)
f(o)= KBT Vc 1 |--ømø + (1 − 6) ln(1 − 6) + x6(1 − ø) N Π II = kBT [ф Vc N X In(1 - 6) - 6- x6² - to:²] = 1 1 + 21 6 No (2.62) (2.66) (3) Following Sec. 2.4.1, using the (mean-field) Flory-Huggin free energy of mixing for a polymer solution (Eq. (2.62)), derive Eq. (2.63) and hence the van't Hoff's law. Show that the coexistence curve is given by (2.66) and compute the critical point. (2.63)
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