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Find parameter values for the Wilson equation that provide the best fit of GE∕RT to the data, and prepare a Pxy diagram that compares the experimental points with curves determined from the correlation.

Find parameter values for the Wilson equation that provide the best fit of GE∕RT to the data, and prepare a Pxy diagram that compares the experimental points with curves determined from the correlation.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Find parameter values for the Wilson equation that provide the best fit of GE∕RT to the data, and prepare a Pxy diagram that compares the experimental points with curves determined from the correlation.

13.34. The following is a set of VLE data for the system acetone(1)/methanol(2) at 55°C: P/kPa X1 yi P/kPa X1 yi 68.728 0.0000 0.0000 97.646 0.5052 0.5844 72.278 0.0287 0.0647 98.462 0.5432 0.6174 75.279 0.0570 0.1295 99.811 0.6332 0.6772 77.524 0.0858 0.1848 99.950 0.6605 0.6926 78.951 0.1046 0.2190 100.278 0.6945 0.7124 82.528 0.1452 0.2694 100.467 0.7327 0.7383 86.762 0.2173 0.3633 100.999 0.7752 0.7729 90.088 0.2787 0.4184 101.059 0.7922 0.7876 93.206 0.3579 0.4779 99.877 0.9080 0.8959 95.017 0.4050 0.5135 99.799 0.9448 0.9336 96.365 0.4480 0.5512 96.885 1.0000 1.0000
Transcribed Image Text:13.34. The following is a set of VLE data for the system acetone(1)/methanol(2) at 55°C: P/kPa X1 yi P/kPa X1 yi 68.728 0.0000 0.0000 97.646 0.5052 0.5844 72.278 0.0287 0.0647 98.462 0.5432 0.6174 75.279 0.0570 0.1295 99.811 0.6332 0.6772 77.524 0.0858 0.1848 99.950 0.6605 0.6926 78.951 0.1046 0.2190 100.278 0.6945 0.7124 82.528 0.1452 0.2694 100.467 0.7327 0.7383 86.762 0.2173 0.3633 100.999 0.7752 0.7729 90.088 0.2787 0.4184 101.059 0.7922 0.7876 93.206 0.3579 0.4779 99.877 0.9080 0.8959 95.017 0.4050 0.5135 99.799 0.9448 0.9336 96.365 0.4480 0.5512 96.885 1.0000 1.0000
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