Figure A. Rate of the reaction with increasing DER concentration while BLOOD and BEN concentrations are constant. 4. Determine the order of the reaction with respect to BEN. Round off the answer to the nearest whole number. 5. Determine the average rate constant. 6. Write the rate law for the reaction.

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 71QAP: For a certain reaction, Ea is 135 kJ and H=45 kJ. In the presence of a catalyst, the activation...
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CHEMICAL KINETICS
AVATAR reaction shown below was subjected to method of initial rates to
determine its rate constant.
BLOOD + BEN + DER → KATARA
The data on the preparation of KATARA and the results of the experiment
are presented below.
Table 1. Data on the preparation of KATARA.
Run 0,375 M of BLOOD 0.06 M of BEN 1M of DER DH20
4.0 mL
2.50 mL
0.25 ml
8.25 mL
2
4,0 mL
10,00 mL
025 mL
0.75 mL
3
8.0 mL
2.50 ml
0.25 L
4.25 ot
Table 2. Data on the determination of rate constant of the formation of
KATARA at 28°C.
Concentration of Concentration of Concentration of
Run
BLOOD, M
Rate of
reaction,
M/s
BEN, M
DER, M
1.
0.10
0.010
0.010
2.0 x 10-2
2
0.040
0.010
7.0 x 10-1
0.010
0.010
3.6 x 10-2
4.00-04
3.50E-04
3.00E-04
250-04
2.00 04
Cate of Reaction, M/s
3.
Transcribed Image Text:CHEMICAL KINETICS AVATAR reaction shown below was subjected to method of initial rates to determine its rate constant. BLOOD + BEN + DER → KATARA The data on the preparation of KATARA and the results of the experiment are presented below. Table 1. Data on the preparation of KATARA. Run 0,375 M of BLOOD 0.06 M of BEN 1M of DER DH20 4.0 mL 2.50 mL 0.25 ml 8.25 mL 2 4,0 mL 10,00 mL 025 mL 0.75 mL 3 8.0 mL 2.50 ml 0.25 L 4.25 ot Table 2. Data on the determination of rate constant of the formation of KATARA at 28°C. Concentration of Concentration of Concentration of Run BLOOD, M Rate of reaction, M/s BEN, M DER, M 1. 0.10 0.010 0.010 2.0 x 10-2 2 0.040 0.010 7.0 x 10-1 0.010 0.010 3.6 x 10-2 4.00-04 3.50E-04 3.00E-04 250-04 2.00 04 Cate of Reaction, M/s 3.
0.01
0.02
0.04
0.0S
0.06
[DER], M
Figure A. Rate of the reaction with increasing DER concentration while
BLOOD and BEN concentrations are constant.
4. Determine the order of the reaction with respect to BEN. Round off
the answer to the nearest whole number.
5. Determine the average rate constant.
6. Write the rate law for the reaction.
Transcribed Image Text:0.01 0.02 0.04 0.0S 0.06 [DER], M Figure A. Rate of the reaction with increasing DER concentration while BLOOD and BEN concentrations are constant. 4. Determine the order of the reaction with respect to BEN. Round off the answer to the nearest whole number. 5. Determine the average rate constant. 6. Write the rate law for the reaction.
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