Fe has both bcc and fcc structures with difference lattice constants: the bcc lattice constant a = 2.8664 Angstrom; and the fcc lattice constant = 3.6468 Angstrom. If we treat Fe atoms as touching hard spheres, (1) Derive associated atomic radius of Fe atoms in the bcc structure (2) Derive associated atomic radius of Fe atoms in the fcc structure (3) Calculate the volume fraction of Fe atoms in the bcc structure

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Fe has both bcc and fcc structures with difference lattice constants: the bcc lattice constant a = 2.8664 Angstrom; and the fcc lattice constant = 3.6468 Angstrom. If we treat Fe atoms as touching hard spheres, (1) Derive associated atomic radius of Fe atoms in the bcc structure (2) Derive associated atomic radius of Fe atoms in the fcc structure (3) Calculate the volume fraction of Fe atoms in the bcc structure (4) Calculate the volume fraction of Fe atoms in the fcc structure (5) Calculate the edge lengths of octahedral and tetrahedral interstitials in bcc Fe (6) Calculate the edge lengths of octahedral and tetrahedral interstitials in fcc Fe (7) The fcc Fe has a denser packed structure yet solubility of carbon (atomic radius 0.7 Angstrom, only can occupy the interstitial sites of Fe) is much higher than that in the bcc Fe. Why is it so?
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