Face-centered simple cubic structure Figure 10.60 lonic compounds with anions that are much larger than cations, such as NaCl, usually form an FCC structure. They can be described by FCC unit cells with cations in the octahedral holes.

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The edge length of the unit cell of LiCl (NaCl-like structure, FCC) is 0.514 nm or 5.14 Å. Assuming that the lithium ion is small enough so that the chloride ions are in contact, as shown, calculate the ionic radius for the chloride ion.
Note: The length unit angstrom, Å, is often used to represent atomic-scale dimensions and is equivalent to 10−10 m.

Face-centered simple cubic structure
Figure 10.60 lonic compounds with anions that are much larger than cations, such as NaCl, usually form an FCC
structure. They can be described by FCC unit cells with cations in the octahedral holes.
Transcribed Image Text:Face-centered simple cubic structure Figure 10.60 lonic compounds with anions that are much larger than cations, such as NaCl, usually form an FCC structure. They can be described by FCC unit cells with cations in the octahedral holes.
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