Explain why the center of the band is used to calculate the Rf value for a cation rather than the leading edge of the band.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Explain why the center of the band is used to calculate the Rf value for a cation rather than the leading edge of the band.

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Polar compounds shows tailing nature during tlc elution (See figure). The center of band is the avarage movement of all molecules eluted. Thus, we can say, movement of center is the avarage movement of bulk. So, for measurement of Rf value for a cation, center of the band is considered for calculation rather than, the leading edge of the band.

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