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Explain the inductive effect (+I and -I) in benzene derivatives.
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- When 2-chloropropane treated with NaOH and 1-chloropropane treated with NaOH separately produce two different functional groups. Provide both reactions and explain the two different functional groups produced.4) Rank the following compounds in order of increasing reactivity (least to most reactive) with respect to acyl substitution. I. methyl benzoate II. benzoylchloride III. benzamide III < | < ||Suggest a possible structure for Compound X.
- Arrange these compounds in order of increasing acidity: 2,4-dichlorophenol, phenol, cyclohexanol.Account for the fact that treating propenoic acid (acrylic acid) with HCl gives only 3-chloropropanoic acid.Enanthotoxin is an extremely poisonous organic compound found in hemlock water drop- wart, which is reputed to be the most poisonous plant in England. It is believed that no British plant has been responsible for more fatal accidents. The most poisonous part of the plant is the roots, which resemble small white carrots, giving the plant the name"five finger death."Also poisonous are its leaves, which look like parsley. Enanthotoxin is thought to interfere with the Nat current in nerve cells, which leads to convulsions and death. он How many stereoisomers are possible for enanthotoxin?
- Which of (a)-(d) is the correct IUPAC name of the following compound? * HO O 3-methyl-1-phenyl-1-pentanol ○ 3-methyl-5-phenyl-5-pentanol ○ 3-methyl-1-benzene-1-pentanol O 1-phenyl-1-hexanolis this correct? Paracetamol consists of an aromatic ring to which a hydroxy group (-OH) is attached, forming a phenol. Attached to the aromatic ring is also an acetamide group, which consists of an acetyl group bound to a nitrogen atom.Predict the products (if any) of the following acid–base reactions.(a) acetic acid + ammonia
- Upon completion of a chemical reaction, you find you have a mixture of benzoic acid and ethyl benzoate. Propose a procedure to separate the ethyl benzoate from the mixture. You should look up the structures of benzoic acid and ethyl benzoate.Which of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4Write in the correct reagents for these transformations: a) cyclohexanol -→ chlorocyclohexane b) 2-butanone 2-butanol ward 2-butanol 2-butanone toluene - → benzoic acid nitrobenzene → aniline
