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Explain the inductive effect (+I and -I) in benzene derivatives.
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- 1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise? 2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia. (i) What do you understand by the term nucleophile? (ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles? 3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?Part c and dWhen 2-chloropropane treated with NaOH and 1-chloropropane treated with NaOH separately produce two different functional groups. Provide both reactions and explain the two different functional groups produced.
- With reference to the structures of acetylsalicylic acid (aspirin, Chapter 2 opening molecule) and acetaminophen (the active ingredient in Tylenol), explain why acetaminophen tablets can be stored in the medicine cabinet for years, but aspirin slowly decomposes over time.4) Rank the following compounds in order of increasing reactivity (least to most reactive) with respect to acyl substitution. I. methyl benzoate II. benzoylchloride III. benzamide III < | < ||Suggest a possible structure for Compound X.
- Account for the fact that treating propenoic acid (acrylic acid) with HCl gives only 3-chloropropanoic acid.Give an example of an azeotrope and give one method/technique that people have used to separate an azeotropic mixture. a) Are cyclohexane and toluene an azeotropic mixture? Why or why not?Give detailed Solution with explanation needed
- Terpineol has 5 isomers. Write their structures and describe why chemically (optically) they receive those names. Number the carbons for a better description.is this correct? Paracetamol consists of an aromatic ring to which a hydroxy group (-OH) is attached, forming a phenol. Attached to the aromatic ring is also an acetamide group, which consists of an acetyl group bound to a nitrogen atom.Determine the structure of the methyl ester and organomagnesium bromide reagents that can be combined to form the following alcohol: Part 1: Draw the bond-line formula for the methyl ester reagent. Disregard stereochemistry. Part 2: Draw the bond-line formula for the organomagnesium bromide reagent. Disregard stereochemistry.
