Experiment for Kinetics – The Iodine Clock Reaction   First part: Results A1: Trial 1: took 43.64 seconds to turn from clear to purple, trail 2: took 44.82 seconds to turn purple, trail 3: which was 47.49 seconds to turn purple, trail 4: was 45.23 seconds to turn purple again, and lastly trail 5: which was 43.63 seconds to turned from clear to purple. Results A2: Trial 1: took 55.10 seconds to turn from clear to purple, trail 2: was 52.77 seconds to turn purple, trail 3: which was 44.67 seconds to turn purple, trail 4: was 59.69 seconds to turn purple again, and lastly trail 5: which was 54.88 seconds to turned from clear to purple. Results A3: Trial 1: took 76 seconds to turn from clear to purple, trail 2: was 88 seconds to turn purple, trail 3: which was 102 seconds to turn purple, trail 4: was 82 seconds to turn purple again, and lastly trail 5: which was 93 seconds to turned from clear to purple. Results A4: Trial 1: took 206.31 seconds to turn purple, trail 2: was 188.55 seconds to turn purple, trail 3: which was 177.13 seconds to turn purple, trail 4: was 199.36 seconds to turn purple again, and lastly trail 5: which was 172.56 seconds to turned from clear to purple. Second part:  Results A1+B in 10 degree: Trial 1: it took 200.4 seconds to turn from clear to purple, trail 2: was 245.4 seconds to turn purple, trail 3: it took 202.8 seconds to turn purple, and trail 4: was 206.4 seconds to turned from clear and purple. Results A2+B in 25 degree: Trial 1: it took 87.7 seconds to turn from clear to purple, trail 2: was 84.36 seconds to turn purple, trail 3: it took 89.51 seconds to turn purple, and trail 4: was 85.54 seconds to turned from clear and purple. Results A3+B of 35 degrees: Trial 1: it took 32.19 seconds to turn from clear to purple after 35 degrees in a hot water bath, trail 2: after in a 35 degrees hot bath was 35.88 seconds to turn purple, trail 3: which was 37.61 seconds to turn purple after a in a hot bath of 35 degrees, and trail 4: was 41.34 seconds to turned from clear and purple after 35 degrees in a water bath. Results A4+B in 45 degree: Trial 1: it took 18.08 seconds to turn from clear to purple, trail 2: was 14.32 seconds to turn purple, trail 3: it took 19.45 seconds to turn purple, and trail 4: was 22.77 seconds to turned from clear and purple.   a) Looking at the rate constants for each trial in the first part of the experiment. Were the rate constants fairly consistent even when varying concentrations? Should they be? How does this compare to the rate constants you calculated for part 2 of the experiment? Should they be the same or different? Be sure elaborate. b) In the second part of the experiment, calculate the activation energy for thereaction. What does this value represent for this reaction? If you were to have used a catalyst for the reaction, what impact do you expect it to have on the activation energy? Explain.

Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter22: Substituted Hydrocarbons And Their Reactions
Section: Chapter Questions
Problem 75A
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Experiment for Kinetics – The Iodine Clock Reaction

 

First part:

Results A1: Trial 1: took 43.64 seconds to turn from clear to purple, trail 2: took 44.82 seconds to turn purple, trail 3: which was 47.49 seconds to turn purple, trail 4: was 45.23 seconds to turn purple again, and lastly trail 5: which was 43.63 seconds to turned from clear to purple.

Results A2: Trial 1: took 55.10 seconds to turn from clear to purple, trail 2: was 52.77 seconds to turn purple, trail 3: which was 44.67 seconds to turn purple, trail 4: was 59.69 seconds to turn purple again, and lastly trail 5: which was 54.88 seconds to turned from clear to purple.

Results A3: Trial 1: took 76 seconds to turn from clear to purple, trail 2: was 88 seconds to turn purple, trail 3: which was 102 seconds to turn purple, trail 4: was 82 seconds to turn purple again, and lastly trail 5: which was 93 seconds to turned from clear to purple.

Results A4: Trial 1: took 206.31 seconds to turn purple, trail 2: was 188.55 seconds to turn purple, trail 3: which was 177.13 seconds to turn purple, trail 4: was 199.36 seconds to turn purple again, and lastly trail 5: which was 172.56 seconds to turned from clear to purple.

Second part: 

Results A1+B in 10 degree: Trial 1: it took 200.4 seconds to turn from clear to purple, trail 2: was 245.4 seconds to turn purple, trail 3: it took 202.8 seconds to turn purple, and trail 4: was 206.4 seconds to turned from clear and purple.

Results A2+B in 25 degree: Trial 1: it took 87.7 seconds to turn from clear to purple, trail 2: was 84.36 seconds to turn purple, trail 3: it took 89.51 seconds to turn purple, and trail 4: was 85.54 seconds to turned from clear and purple.

Results A3+B of 35 degrees: Trial 1: it took 32.19 seconds to turn from clear to purple after 35 degrees in a hot water bath, trail 2: after in a 35 degrees hot bath was 35.88 seconds to turn purple, trail 3: which was 37.61 seconds to turn purple after a in a hot bath of 35 degrees, and trail 4: was 41.34 seconds to turned from clear and purple after 35 degrees in a water bath.

Results A4+B in 45 degree: Trial 1: it took 18.08 seconds to turn from clear to purple, trail 2: was 14.32 seconds to turn purple, trail 3: it took 19.45 seconds to turn purple, and trail 4: was 22.77 seconds to turned from clear and purple.

 

a) Looking at the rate constants for each trial in the first part of the experiment. Were the rate constants fairly consistent even when varying concentrations? Should they be? How does this compare to the rate constants you calculated for part 2 of the experiment? Should they be the same or different? Be sure elaborate.


b) In the second part of the experiment, calculate the activation energy for thereaction. What does this value represent for this reaction? If you were to have used a catalyst for the reaction, what impact do you expect it to have on the activation energy? Explain.

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