EXPERIMENT 18 ELECTROCHEMISTRY AND THERMODYNAMICS Data Table 3. Determination of AH and AS. Balanced redox equation for the cells: Temperature, °C E, V Temperature, °C E, V Temperature, °C E, V 72.0 70.0 0.668 0.6670 0.6670 0.638 う6.0 40.0 38.0 0.657 54.0 0.0ol00 0.L0662 0.642 68.0 0.6644 366.0 34.0 32.0 52.0 0.L671 0.6672 6l6.0 0.645 50.0 0.Lole 3 0.650 0.lo65 0.Lelole 64.0 62.0 60.0 う8.0 48.0 46.0 니4.0 0.652 0.653 0-667 0.6655 42.0 0.Lol07 R² Equation of line ΔΗ AS Error Analysis Questions: Using the following published data, calculate the theoretical values of AH and AS of the Zn-Cu cell system. Use stoichiometric multipliers and units in the equations. 1. 2+ Zn Zn Cu Cu* 2+ AH, kJ/mol ΔΗ, 0. -152.4 51.88 41.6 -106.48 33.3 -26.4 AS, J/mol-K AH: AS: In voltaic cell, if E is AG is and K is . The 2. and the equilibrium lies with the reaction is Why are voltaic and electrolytic cell reactions compared using voltages instead of K 3. values? 279

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Question
EXPERIMENT 18
ELECTROCHEMISTRY AND THERMODYNAMICS
Data Table 3. Determination of AH and AS.
Balanced redox equation for the cells:
Temperature, °C
E, V
Temperature, °C
E, V
Temperature, °C
E, V
72.0
70.0
0.668
0.6670
0.6670
0.638
う6.0
40.0
38.0
0.657
54.0
0.0ol00
0.L0662
0.642
68.0
0.6644
366.0
34.0
32.0
52.0
0.L671
0.6672
6l6.0
0.645
50.0
0.Lole 3
0.650
0.lo65
0.Lelole
64.0
62.0
60.0
う8.0
48.0
46.0
니4.0
0.652
0.653
0-667
0.6655
42.0
0.Lol07
R²
Equation of line
ΔΗ
AS
Error Analysis Questions:
Using the following published data, calculate the theoretical values of AH and AS of
the Zn-Cu cell system. Use stoichiometric multipliers and units in the equations.
1.
2+
Zn
Zn
Cu
Cu*
2+
AH, kJ/mol
ΔΗ,
0.
-152.4
51.88
41.6
-106.48
33.3
-26.4
AS, J/mol-K
AH:
AS:
In voltaic cell, if E is
AG is
and K is
. The
2.
and the equilibrium lies with the
reaction is
Why are voltaic and electrolytic cell reactions compared using voltages instead of K
3.
values?
279
Transcribed Image Text:EXPERIMENT 18 ELECTROCHEMISTRY AND THERMODYNAMICS Data Table 3. Determination of AH and AS. Balanced redox equation for the cells: Temperature, °C E, V Temperature, °C E, V Temperature, °C E, V 72.0 70.0 0.668 0.6670 0.6670 0.638 う6.0 40.0 38.0 0.657 54.0 0.0ol00 0.L0662 0.642 68.0 0.6644 366.0 34.0 32.0 52.0 0.L671 0.6672 6l6.0 0.645 50.0 0.Lole 3 0.650 0.lo65 0.Lelole 64.0 62.0 60.0 う8.0 48.0 46.0 니4.0 0.652 0.653 0-667 0.6655 42.0 0.Lol07 R² Equation of line ΔΗ AS Error Analysis Questions: Using the following published data, calculate the theoretical values of AH and AS of the Zn-Cu cell system. Use stoichiometric multipliers and units in the equations. 1. 2+ Zn Zn Cu Cu* 2+ AH, kJ/mol ΔΗ, 0. -152.4 51.88 41.6 -106.48 33.3 -26.4 AS, J/mol-K AH: AS: In voltaic cell, if E is AG is and K is . The 2. and the equilibrium lies with the reaction is Why are voltaic and electrolytic cell reactions compared using voltages instead of K 3. values? 279
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