Exercise For the reaction H₂O₂ + 2H+ + 21-1₂ + 2H₂O in acidic aqueous solution, the rate law (7) in (16.6) indicates the reaction proceeds by two simultaneous mechanisms. Suppose one mechanism is H + I HI rapid equilib. HI + H₂O₂ → H₂O + HOI slow HOI + II₂ + OH™ fast OH + HH₂O fast Verify that this mechanism adds to the correct overall reaction. Find the rate law predicted by this mechanism. (Answer: r = k[H₂O₂][H+][I].)
Exercise For the reaction H₂O₂ + 2H+ + 21-1₂ + 2H₂O in acidic aqueous solution, the rate law (7) in (16.6) indicates the reaction proceeds by two simultaneous mechanisms. Suppose one mechanism is H + I HI rapid equilib. HI + H₂O₂ → H₂O + HOI slow HOI + II₂ + OH™ fast OH + HH₂O fast Verify that this mechanism adds to the correct overall reaction. Find the rate law predicted by this mechanism. (Answer: r = k[H₂O₂][H+][I].)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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