EXAMPLE 13.4 The conversion of cyclopropane to propene in the gas phase is a first-order reaction with a rate constant of 6.7 × 10~ª s¬1 at 500°C. CH2 → CH3-CH=CH2 CH,-CH2 cyclopropane propene (a) If the initial concentration of cyclopropane was 0.25 M, what is the concentration after 8.8 min? (b) How long (in minutes) will it take for the concentration of cyclopropane to decrease from 0.25 M to 0.15 M? (c) How long (in minutes) will it take to convert 74 percent of the starting material?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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provide the given, required, and do the cancellations.
EXAMPLE 13.4
The conversion of cyclopropane to propene in the gas phase is a first-order reaction
with a rate constant of 6.7 × 10~* s¬1 at 500°C.
CH2
→ CH3-CH=CH2
CH,-CH2
cyclopropane
propene
(a) If the initial concentration of cyclopropane was 0.25 M, what is the concentration
after 8.8 min? (b) How long (in minutes) will it take for the concentration of
cyclopropane to decrease from 0.25 M to 0.15 M? (c) How long (in minutes) will it
take to convert 74 percent of the starting material?
Transcribed Image Text:EXAMPLE 13.4 The conversion of cyclopropane to propene in the gas phase is a first-order reaction with a rate constant of 6.7 × 10~* s¬1 at 500°C. CH2 → CH3-CH=CH2 CH,-CH2 cyclopropane propene (a) If the initial concentration of cyclopropane was 0.25 M, what is the concentration after 8.8 min? (b) How long (in minutes) will it take for the concentration of cyclopropane to decrease from 0.25 M to 0.15 M? (c) How long (in minutes) will it take to convert 74 percent of the starting material?
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