Ethylene glycol, the primary ingredient in antifreeze, has the chemical formula C₂H6O₂. The radiator fluid used i most cars is a half-and-half mixture of water and antifreeze. What is the freezing point of radiator fluid that is 50% antifreeze by mass? K for water is 1.86 °C/m. Express your answer to three significant figures and include the appropriate units. ► View Available Hint(s) μA Value LO What is the boiling point of radiator fluid that is 50% antifreeze by mass? Kh for water is 0.512 °C/m. Express your answer to one decimal place and include the appropriate units. ► View Available Hint(s) μÅ Units Value ? Units ?

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The boiling point and freezing points of a solution differs from those of the pure
liquid. This can be explained in terms of vapor pressure. Since the vapor
pressure of the solvent above the solution is lower, a higher temperature is
needed to reach a point where the vapor pressure of the liquid meets the
required 1 atm, and the boiling point is elevated. The lower vapor pressure
changes the entire phase diagram for the solvent, and the resulting change
pushes the triple point of the solution to a lower temperature value. The solid-
liquid phase equilibria curve is related to the location of the triple point, and the
freezing point is also lower.
The change in the boiling point for a solution containing a molecular solute,
AT, can be calculated using the equation
ATb = Kb.m
in which m is the molality of the solution and K₁ is the molal boiling-point-
elevation constant for the solvent. The freezing-point depression, ATF, can be
calculated in a similar manner using
AT₁ = Kf.m
in which m is the molality of the solution and Kf is the molal freezing-point-
depression constant for the solvent.
Transcribed Image Text:The boiling point and freezing points of a solution differs from those of the pure liquid. This can be explained in terms of vapor pressure. Since the vapor pressure of the solvent above the solution is lower, a higher temperature is needed to reach a point where the vapor pressure of the liquid meets the required 1 atm, and the boiling point is elevated. The lower vapor pressure changes the entire phase diagram for the solvent, and the resulting change pushes the triple point of the solution to a lower temperature value. The solid- liquid phase equilibria curve is related to the location of the triple point, and the freezing point is also lower. The change in the boiling point for a solution containing a molecular solute, AT, can be calculated using the equation ATb = Kb.m in which m is the molality of the solution and K₁ is the molal boiling-point- elevation constant for the solvent. The freezing-point depression, ATF, can be calculated in a similar manner using AT₁ = Kf.m in which m is the molality of the solution and Kf is the molal freezing-point- depression constant for the solvent.
Ethylene glycol, the primary ingredient in antifreeze, has the chemical formula C₂H6O₂. The radiator fluid used in most cars is a half-and-half mixture of water and antifreeze.
What is the freezing point of radiator fluid that is 50% antifreeze by mass?
Kf for water is 1.86 °C/m.
Express your answer to three significant figures and include the appropriate units.
► View Available Hint(s)
μA
Value
HÅ
Units
What is the boiling point of radiator fluid that is 50% antifreeze by mass?
K for water is 0.512 °C/m.
Express your answer to one decimal place and include the appropriate units.
▸ View Available Hint(s)
Value
?
Units
?
Transcribed Image Text:Ethylene glycol, the primary ingredient in antifreeze, has the chemical formula C₂H6O₂. The radiator fluid used in most cars is a half-and-half mixture of water and antifreeze. What is the freezing point of radiator fluid that is 50% antifreeze by mass? Kf for water is 1.86 °C/m. Express your answer to three significant figures and include the appropriate units. ► View Available Hint(s) μA Value HÅ Units What is the boiling point of radiator fluid that is 50% antifreeze by mass? K for water is 0.512 °C/m. Express your answer to one decimal place and include the appropriate units. ▸ View Available Hint(s) Value ? Units ?
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