Estimate Z, HR, and SR for one of the following equimolar mixtures by the Lee/Kesler correlations: (h) Nitrogen/oxygen at 250 K and 100 bar.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Problem 1.1P
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Estimate Z, HR, and SR for one of the following equimolar mixtures by the Lee/Kesler
correlations:
(h) Nitrogen/oxygen at 250 K and 100 bar.

 

Molar
Ve
cm³-mol-1 TK
T/K
P /bar
Ze
mass
Ethylene glycol
62.068
0.487 719.7
77.00 0.246
191.0
470.5
Acetic acid
60.053
0.467 592.0
57.86 0.211
179.7
391.1
n-Butyric acid
88.106
0.681
615.7
40.64 0.232
291.7
436.4
Benzoic acid
122.123
0.603
751.0
44.70 0.246
344.
522.4
Acetonitrile
41.053
0.338
545.5
48.30 0.184
173.
354.8
Methylamine
Ethylamine
31.057
0.281
430.1
74.60 0.321
154.
266.8
45.084
0.285 456.2
56.20 0.307
207.
289.7
Nitromethane
61.040
0.348 588.2
63.10 0.223
173.
374.4
Carbon tetrachloride
153.822
0.193 556.4
45.60 0.272
276.
349.8
Chloroform
119.377
0.222 536.4
54.72 0.293
239.
334.3
Dichloromethane
84.932
0.199 510.0
60.80 0.265
185.
312.9
Methyl chloride
Ethyl chloride
Chlorobenzene
50.488
0.153 416.3
66.80 0.276
143.
249.1
64.514
0.190 460.4
52.70 0.275
200.
285.4
112.558
0.250 632.4
45.20 0.265
308.
404.9
Tetrafluoroethane
102.030
0.327 374.2
40.60 0.258
198.0
247.1
Argon
Krypton
Xenon
39.948
0.000
150.9
48.98 0.291
74.6
87.3
83.800
0.000 209.4
55.02 0.288
91.2
119.8
131.30
0.000 289.7
58.40 0.286
118.0
165.0
Helium 4
4.003 -0.390
5.2
2.28 0.302
57.3
4.2
64.1
Hydrogen
Охуgen
Nitrogen
Airt
2.016 -0.216 33.19
13.13 0.305
20.4
31.999
0.022 154.6
50.43 0.288
73.4
90.2
28.014
0.038 126.2
34.00 0.289
89.2
77.3
28.851
0.035 132.2
37.45
0.289
84.8
Chlorine
70.905
0.069
417.2
77.10 0.265
124.
239.1
Carbon monoxide
28.010
0.048
132.9
34.99 0.299
93.4
81.7
Carbon dioxide
44.010
0.224 304.2
73.83 0.274
94.0
Carbon disulfide
76.143
0.111
552.0
79.00 0.275
160.
319.4
Hydrogen sulfide
34.082
0.094
373.5
89.63 0.284
98.5
212.8
Transcribed Image Text:Molar Ve cm³-mol-1 TK T/K P /bar Ze mass Ethylene glycol 62.068 0.487 719.7 77.00 0.246 191.0 470.5 Acetic acid 60.053 0.467 592.0 57.86 0.211 179.7 391.1 n-Butyric acid 88.106 0.681 615.7 40.64 0.232 291.7 436.4 Benzoic acid 122.123 0.603 751.0 44.70 0.246 344. 522.4 Acetonitrile 41.053 0.338 545.5 48.30 0.184 173. 354.8 Methylamine Ethylamine 31.057 0.281 430.1 74.60 0.321 154. 266.8 45.084 0.285 456.2 56.20 0.307 207. 289.7 Nitromethane 61.040 0.348 588.2 63.10 0.223 173. 374.4 Carbon tetrachloride 153.822 0.193 556.4 45.60 0.272 276. 349.8 Chloroform 119.377 0.222 536.4 54.72 0.293 239. 334.3 Dichloromethane 84.932 0.199 510.0 60.80 0.265 185. 312.9 Methyl chloride Ethyl chloride Chlorobenzene 50.488 0.153 416.3 66.80 0.276 143. 249.1 64.514 0.190 460.4 52.70 0.275 200. 285.4 112.558 0.250 632.4 45.20 0.265 308. 404.9 Tetrafluoroethane 102.030 0.327 374.2 40.60 0.258 198.0 247.1 Argon Krypton Xenon 39.948 0.000 150.9 48.98 0.291 74.6 87.3 83.800 0.000 209.4 55.02 0.288 91.2 119.8 131.30 0.000 289.7 58.40 0.286 118.0 165.0 Helium 4 4.003 -0.390 5.2 2.28 0.302 57.3 4.2 64.1 Hydrogen Охуgen Nitrogen Airt 2.016 -0.216 33.19 13.13 0.305 20.4 31.999 0.022 154.6 50.43 0.288 73.4 90.2 28.014 0.038 126.2 34.00 0.289 89.2 77.3 28.851 0.035 132.2 37.45 0.289 84.8 Chlorine 70.905 0.069 417.2 77.10 0.265 124. 239.1 Carbon monoxide 28.010 0.048 132.9 34.99 0.299 93.4 81.7 Carbon dioxide 44.010 0.224 304.2 73.83 0.274 94.0 Carbon disulfide 76.143 0.111 552.0 79.00 0.275 160. 319.4 Hydrogen sulfide 34.082 0.094 373.5 89.63 0.284 98.5 212.8
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