electrophilic %3D CH-CCH3 CH2=C-CH3 CH3-C-CH3

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Aldol condensations, even with ketones, can
occur under acid conditions where the active
nucleophile is the enol, not the enolate ion. For
the aldol condensation shown for acetone, what
would be the structure of the electrophilic
species that the enol attacks?
CH3
H. c=CH-CCH3
CH3
%3D
CH3CCH3
он
(A)
CH2=C-CH3
(B)
CH2=C-CH3
*o-H
CH3-C-CH3
(D)
(C)
CH3-C-CH3
%3D
Which compound when
treated with NaOCH,
followed by neutralization
with aqueous acid will
produce this B-diketone?
Transcribed Image Text:Aldol condensations, even with ketones, can occur under acid conditions where the active nucleophile is the enol, not the enolate ion. For the aldol condensation shown for acetone, what would be the structure of the electrophilic species that the enol attacks? CH3 H. c=CH-CCH3 CH3 %3D CH3CCH3 он (A) CH2=C-CH3 (B) CH2=C-CH3 *o-H CH3-C-CH3 (D) (C) CH3-C-CH3 %3D Which compound when treated with NaOCH, followed by neutralization with aqueous acid will produce this B-diketone?
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