Physical Chemistry 2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Ball, David W. (david Warren), BAER, Tomas
1 Gases And The Zeroth Law Of Thermodynamics 2 The First Law Of Thermodynamics 3 The Second And Third Laws Of Thermodynamics 4 Gibbs Energy And Chemical Potential 5 Introduction To Chemical Equilibrium 6 Equilibria In Single-component Systems 7 Equilibria In Multiple-component Systems 8 Electrochemistry And Ionic Solutions 9 Pre-quantum Mechanics 10 Introduction To Quantum Mechanics 11 Quantum Mechanics: Model Systems And The Hydrogen Atom 12 Atoms And Molecules 13 Introduction To Symmetry In Quantum Mechanics 14 Rotational And Vibrational Spectroscopy 15 Introduction To Electronic Spectroscopy And Structure 16 Introduction To Magnetic Spectroscopy 17 Statistical Thermodynamics: Introduction 18 More Statistical Thermodynamics 19 The Kinetic Theory Of Gases 20 Kinetics 21 The Solid State: Crystals 22 Surfaces Chapter1: Gases And The Zeroth Law Of Thermodynamics
Chapter Questions Section: Chapter Questions
Problem 1.1E: A bomb calorimeter is a study metal vessel in which samples can be ignited and the amount of heat... Problem 1.2E: Difference between the system and the surroundings. Give examples of both. Problem 1.3E Problem 1.4E Problem 1.5E Problem 1.6E Problem 1.7E Problem 1.8E: A pot of cold water is heated on a stove, and when the water boils, a fresh egg is placed in the... Problem 1.9E: hat difference is necessary for heat to flow between two systems? Can you think of an exception to... Problem 1.10E: What is the value of FT for a sample of gas whose volume is 2.97 L and pressure is 0.0553 atm? What... Problem 1.11E: What is the value of FP for a sample of gas whose temperature is -33.0 C and volume is 0.0250 L?... Problem 1.12E Problem 1.13E: Hydrogen gas is used in weather balloon because it is less expensive than Helium. Assume that 5.57 g... Problem 1.14E Problem 1.15E: A 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to... Problem 1.16E: The Mount Pinatubo volcano eruption in 1991 released an estimated 1.82 x 1013g of SO2 into the... Problem 1.17E Problem 1.18E: Scottish physicist W. J. M. Rankine proposed an absolute temperature scale based on the Fahrenheit... Problem 1.19E: Use the two appropriate values of R to determine a conversion between L. atm and J. Problem 1.20E Problem 1.21E: Pressures of gases in mixtures are referred to as partial pressures and are additive. 1.00 L of He... Problem 1.22E: Earths atmosphere is approximately 80 N2 and 20 O2. If the total atmospheric pressure at sea level... Problem 1.23E: The atmospheric surface pressure on Venus is 90 bar and is composed of 96 carbon dioxide and... Problem 1.24E Problem 1.25E Problem 1.26E: In the anaerobic oxidation of glucose by yeast, CO2 is produced: If 1.56 L of CO2 were produced at... Problem 1.27E: What are the slopes of the following lines at the point x = 5? At x = 10? a y = 5x 7 b y = 3x2 5x ... Problem 1.28E: For the following function, evaluate the derivatives in a-f below. F(w,x,y,z)=3xy2+w3z332yxy2z3w... Problem 1.29E: Determine the expressions for the following, assuming that the ideal gas law holds. Problem 1.30E: Determine the expressions for the following, assuming that the ideal gas law holds. Problem 1.31E Problem 1.32E Problem 1.33E Problem 1.34E Problem 1.35E: What properties of a nonideal gas do the Vander Waals constants represent? Problem 1.36E Problem 1.37E Problem 1.38E: Calculate the Boyle temperatures for carbon dioxide, oxygen, and nitrogen using the van der Waals... Problem 1.39E Problem 1.40E Problem 1.41E: Table 1.4 show that the second virial coefficient B for He is negative at low temperature, seems to... Problem 1.42E Problem 1.43E: What is the van der Waals constant a for Ne in units of bar.cm6/mol2 Problem 1.44E Problem 1.45E: Under what conditions would the van der Waals constant b be negative? Do you think there are any... Problem 1.46E: By definition, the compressibility of an ideal gas is 1. By approximately what percentage does this... Problem 1.47E: The second virial coefficient B and the third viral coefficient C for Ar are -0.021 L/mol and 0.0012... Problem 1.48E: Use the approximation 1 x-1 1 x x2 to determine an expression for the virial coefficient C in... Problem 1.49E: Why is nitrogen a good choice for the study of ideal gas behavior around room temperature? Problem 1.50E: Evaluate for a gas following the Redlich-Kwong equation of state? pV Problem 1.51E: Numerically evaluate for one mole of methane acting as a van der Waals gas at a T = 298 K and V =... Problem 1.52E: Under what conditions of volume does a van der Waals gas behave like an ideal gas? Use the van der... Problem 1.53E: At high temperatures, one of the van der Waals constants can be ignored. Which one? Justify your... Problem 1.54E: Under what conditions of temperature does a Redlich-Kwong gas behave like an ideal gas? Use the... Problem 1.55E: The Berthelot equation of state for one mole of gas is p=RTV-b-aTV2 Where a and b are constants... Problem 1.56E Problem 1.57E: Referring to exercises 1.6 and 1.7, does it matter if the pressure difference is caused by an ideal... Problem 1.58E Problem 1.59E: Use Figure 1.11 to construct the cyclic rule equivalent of Does the answer make sense in light of... Problem 1.60E Problem 1.61E Problem 1.62E: Calculate for one mole of an ideal gas at STP and SATP. Problem 1.63E Problem 1.64E: Show that = T/p for an ideal gas. Problem 1.65E: Determine an expression for V/T p, n in terms of and . Does the sign on the expression make sense... Problem 1.66E Problem 1.67E Problem 1.68E: Perform a units analysis on the exponent of the barometric function and verify that the overall... Problem 1.69E: Using the barometric formula, calculate the expected air pressure in Colorado Springs, Colorado,... Problem 1.70E: The barometric formula can also be used for elevations below sea level. In such cases, h is... Problem 1.71E Problem 1.72E Problem 1.73E Problem 1.74E Problem 1.75E Problem 1.76E Problem 1.77E Problem 1.78E Problem 1.79E Problem 1.80E: Use the ideal gas law to symbolically prove the cyclic rule of partial derivatives. Problem 1.81E Problem 1.77E
Related questions
Transcribed Image Text: arn
Energy
2
GURE 13.12
Electronic
Excited State
Electronic
Ground State
Questions:
How to describe these electronic terms?
How to describe these vibrational terms?
➤ How to describe these rotation terms?
> Can all those transitions experimentally observed?
➤What means "forbidden transition"?
➤What are "selection rules"?
Branch of physics that deals with the behavior of particles at a subatomic level.
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