EDTA is a hexaprotic system with the pKa values: -ooC-CH2 H,C-COO pKal 0.00, pK2 = 1.50, pKa3 = 2.00, pKa4 = 2.69, :N-CH2-CH2-N: pKa5 = 6.13, and pKa6 OOC-CH2 H2C-COO The distribution of the various protonated forms of EDTA EDTA (or Y4) will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA, it is convenient to calculate the fraction of EDTA that is in the completely unprotonated form, Y. This fraction is designated ays-. Calculate ayi- at two pH values. 4.41 pH = 3.60 %3D Incorrect 8.25 pH = 10.80 dy4- =

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EDTA is a hexaprotic system with the pKa values:
-OOC-CH2
H2C-COO
pKal = 0.00, pK2 = 1.50, pK3 = 2.00, pK4 = 2.69,
:N-CH2-CH2-N:
pKa5 = 6.13, and pKa6
10.37.
OOC-CH2
H2C-COO
The distribution of the various protonated forms of EDTA
EDTA- (or Y4-)
will therefore vary with pH. For equilibrium calculations
involving metal complexes with EDTA, it is convenient to
calculate the fraction of EDTA that is in the completely
unprotonated form, Y. This fraction is designated ays-.
Calculate ayt- at two pH values.
4.41
pH = 3.60
Incorrect
8.25
pH
10.80
Transcribed Image Text:EDTA is a hexaprotic system with the pKa values: -OOC-CH2 H2C-COO pKal = 0.00, pK2 = 1.50, pK3 = 2.00, pK4 = 2.69, :N-CH2-CH2-N: pKa5 = 6.13, and pKa6 10.37. OOC-CH2 H2C-COO The distribution of the various protonated forms of EDTA EDTA- (or Y4-) will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA, it is convenient to calculate the fraction of EDTA that is in the completely unprotonated form, Y. This fraction is designated ays-. Calculate ayt- at two pH values. 4.41 pH = 3.60 Incorrect 8.25 pH 10.80
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