DSSUR                                                                                                                                                                                      (give units)                                                                                                                         DSTOT                                                                                                                                                                                                                                                    (give units)     (B) Does the spontaneity of this reaction change with temperature?  Please explain.  If there is a crossover temperature, calculate it.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1.) Here is the reaction of carbon monoxide and hydrogen to form gaseous methanol at 298 K.

This reaction is spontaneous at 298 K under standard conditions.  

CO (g) + 2 H2 (g)   CH3OH (g

Substance

DHfo kJ/mol

      So         J/(K mol)

CH3OH (g) 

-201

239.9

H2 (g)

 

130.7

CO (g)

-110.5

197.7

(A) What is DSSUR in this problem?  What is DSTOT?  Is this consistent with your answer to (e)?

Please explain.   

 

                                                                                                                        DSSUR                                                                                                                                                                                      (give units)

                                                                                                                        DSTOT                                        

                                                                                                                                                                                                           (give units)  

 

(B) Does the spontaneity of this reaction change with temperature?  Please explain.  If there is a crossover temperature, calculate it.

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