Drives above thermodynamic quantities from the partition function Z. Function of state Statistical mechanical expression d In Z U dB -kgT In Z F (), Əln Z U-F S -(等)。=早 kg In Z + kgT V Əln Z av Əln Z (部)r kgT P = - = U + pV kpT T( Əln Z av H +V ´Əln Z G = F +pV = H –TS kgT|- In Z +V av a²În Z +T ´Əln Z Cv = ()v kgT |2 %3D V
Drives above thermodynamic quantities from the partition function Z. Function of state Statistical mechanical expression d In Z U dB -kgT In Z F (), Əln Z U-F S -(等)。=早 kg In Z + kgT V Əln Z av Əln Z (部)r kgT P = - = U + pV kpT T( Əln Z av H +V ´Əln Z G = F +pV = H –TS kgT|- In Z +V av a²În Z +T ´Əln Z Cv = ()v kgT |2 %3D V
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Transcribed Image Text:Drives above thermodynamic quantities from the partition function Z.
Function of state
Statistical mechanical expression
d In Z
dB
-kgT In Z
U
F
Əln Z
().
U-F
S
-(等)ル=リ
kg ln Z + kgT
%3D
()r
Əln Z
kBT (
= -
av
´Əln Ž
= U +pV
kgT |T
´Əln Z
+V
H
ƏT
av
( Əln Z
G
= F + pV = H –TS kgT|-In Z +V
aV
Əln Z
),
2²ln Z
Cy = ()v
kgT |2
+T
ƏT2
V
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