Draw the two possible chair conformations of the (+)- B- Galactose molecule shown below, using the axial and equatorial bonds provided. Show all substituents and hydrogens. 4. CH-ОН HO ОН ОН CH2OH CHON OH HO OH HO OH HO H OH OH Conformation # 1 Conformation # 2 5. With respect to the previous problem # 4, and your two chair conformations of (+)- B- Galactose.. A single (-OH -- H) 1,3-diaxial steric strain interaction is 2.1 kJ/mole, and a single (-CH2OH -- H) 1,3-diaxial steric strain interaction is 4.0 kJ/mole, and finally a single (-CH2OH steric strain interaction is 4.6 kJ/mole. OH) 1,3-diaxial Determine and Show Calculations for the total 1,3-diaxial steric strain contained in your a) conformations # 1 and # 2. b) Indicate which of your chair conformations is the most stable. Conformation # 1 Conformation # 2 3 Hr

Draw the two possible chair conformations of the (+)- B- Galactose molecule shown below, using the axial and equatorial bonds provided. Show all substituents and hydrogens. 4. CH-ОН HO ОН ОН CH2OH CHON OH HO OH HO OH HO H OH OH Conformation # 1 Conformation # 2 5. With respect to the previous problem # 4, and your two chair conformations of (+)- B- Galactose.. A single (-OH -- H) 1,3-diaxial steric strain interaction is 2.1 kJ/mole, and a single (-CH2OH -- H) 1,3-diaxial steric strain interaction is 4.0 kJ/mole, and finally a single (-CH2OH steric strain interaction is 4.6 kJ/mole. OH) 1,3-diaxial Determine and Show Calculations for the total 1,3-diaxial steric strain contained in your a) conformations # 1 and # 2. b) Indicate which of your chair conformations is the most stable. Conformation # 1 Conformation # 2 3 Hr

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Draw the two possible chair conformations of the (+)- B- Galactose molecule shown below, using the
axial and equatorial bonds provided. Show all substituents and hydrogens.
4.
CH-ОН
HO
ОН
ОН
CH2OH
CHON
OH
HO
OH
HO
OH
HO
H
OH
OH
Conformation # 1
Conformation # 2
5.
With respect to the previous problem # 4, and your two chair conformations of (+)- B- Galactose..
A single (-OH -- H) 1,3-diaxial steric strain interaction is 2.1 kJ/mole, and a single (-CH2OH -- H)
1,3-diaxial steric strain interaction is 4.0 kJ/mole, and finally a single (-CH2OH
steric strain interaction is 4.6 kJ/mole.
OH) 1,3-diaxial
Determine and Show Calculations for the total 1,3-diaxial steric strain contained in your
a)
conformations # 1 and # 2.
b)
Indicate which of your chair conformations is the most stable.
Conformation # 1
Conformation # 2
3
Hr

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CONCLUSIONS: In general, the boiling points of compounds increase down a group in the periodic table. The melting points and boiling points for the hydrogen compounds of group 6A elements are in the table below. Melting Point (°C) Boiling Point (°C) H₂O 0.0 100.0 H₂S -82.0 -60.0 H₂Se -65.7 -41.2 H₂Te -49.0 -2.2 Use your understanding of chemistry to propose an explanation for the anomaly in the trend for the hydrogen compounds of group 6A elements shown in the table.