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Draw the three products made during this ortho-para directing reaction, keeping in mind that deuterium (D) is an isotope of hydrogen and reacts in much the same way as a hydrogen. OH HNO3 H₂SO4

Draw the three products made during this ortho-para directing reaction, keeping in mind that deuterium (D) is an isotope of hydrogen and reacts in much the same way as a hydrogen. OH HNO3 H₂SO4

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question 9:** **Draw** the three products made during this ortho-para directing reaction, keeping in mind that deuterium (D) is an isotope of hydrogen and reacts in much the same way as a hydrogen. **Chemical Reaction:** - The diagram depicts a benzene ring with a hydroxyl group (OH) attached as a substituent, along with deuterium (D). - Reagents involved are nitric acid (HNO₃) and sulfuric acid (H₂SO₄), indicating that this is a nitration reaction. - The hydroxyl group will direct the incoming nitro groups (NO₂) to the ortho and para positions relative to its location on the benzene ring. **Explanation:** This reaction involves the nitration of phenol (with deuterium substitution), which commonly occurs at ortho- and para- positions due to the directing effects of the hydroxyl group. The challenge is to draw and identify the resulting orthonitrophenol, paranitrophenol, and meta-nitrophenol as minor product, keeping in mind the stability and substitution pattern specific to ortho-para directing groups.
Transcribed Image Text:**Question 9:** **Draw** the three products made during this ortho-para directing reaction, keeping in mind that deuterium (D) is an isotope of hydrogen and reacts in much the same way as a hydrogen. **Chemical Reaction:** - The diagram depicts a benzene ring with a hydroxyl group (OH) attached as a substituent, along with deuterium (D). - Reagents involved are nitric acid (HNO₃) and sulfuric acid (H₂SO₄), indicating that this is a nitration reaction. - The hydroxyl group will direct the incoming nitro groups (NO₂) to the ortho and para positions relative to its location on the benzene ring. **Explanation:** This reaction involves the nitration of phenol (with deuterium substitution), which commonly occurs at ortho- and para- positions due to the directing effects of the hydroxyl group. The challenge is to draw and identify the resulting orthonitrophenol, paranitrophenol, and meta-nitrophenol as minor product, keeping in mind the stability and substitution pattern specific to ortho-para directing groups.
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