Draw the structures of organic compounds A and B. Indicate stereochemistry where applicable HIC C-H 1. NaNH, 2. CH3CH₂CH₂Br (1 equiv.) Draw compound A. Select Draw Templates More / |||||| C H compound A Erase H₂ Lindlar's catalyst compound B Draw compound B. H₂O H3O+ Select Draw Templates More C H OH Era

Draw the structures of organic compounds A and B. Indicate stereochemistry where applicable HIC C-H 1. NaNH, 2. CH3CH₂CH₂Br (1 equiv.) Draw compound A. Select Draw Templates More / |||||| C H compound A Erase H₂ Lindlar's catalyst compound B Draw compound B. H₂O H3O+ Select Draw Templates More C H OH Era

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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7). Which of the following reactions is incorrect? Answer A) H₂O. B) D) E) M OH A) +Bry H₂O „O'LI* CH₂ -CH₂Br H₂O 1.CH₂MgBr 2.H₂0 aya 2) H₂O* + NaOH 8. What is the main product of the following reaction sequence? Answer B) Br CH,Br OH CH₂ OH H Na Br₂ H₂O* Br -CH₂ + H₂O D)
n progress structural formula for the substitution product of the reaction shown below. Br NH3 CH3OH Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one stereoisomer of product is formed, draw both. • Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms.
IRW O Draw the neutral organic product for the reaction shown. Show stereochemistry clearly. % V Q Search 5 G f6 1. 2 Li, C2H5NH2, –78 °C 2. NHẠCH 6 B Y 17 & H 7 lipi N fg * Select Draw Templates More 8 / ||| ||| Ś Ć N fg M 4 9 K C O f10 H f12 2 Q + Learning Erase BANG & OLUFSEN insert 1 F
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Macmillan Learning Draw the major E2 reaction product formed when trans-1-chloro-2-ethylcyclohexane (shown) reacts with hydroxide ion in DMSO. H H- H H H H H H CI CH₂CH3 HO™ DMSO Select Draw Templates More / |||||| 3 Ć C H O Q2 Q Erase
10. Allylic bromination of 4-methyl-2-pentene could form products J-L. NBS Br hv Br Br J K Of products J-L, which is more likely to be the major product? Explain. a. eldiecog lis wsb betasys 2i suxim pcng noiss b. Explain how product M is also possible for this reaction. Br M can
What is the product of the following reaction sequence? 1) MeMgBr (excess) 2) Hа0 HO SOCI2 H2SO4, heat ОН I. I. LOH OH II. IV. O i. only iii. only none of the other answer choices are correct O ii. only O iv. only
A. Draw the products resulting from addition of a Grignard reagent to an aldehyde. ■■Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicablelgnore any inorganic byproducts. + 1) PhMgCl (CH.MgC 2) HO/HO Select Ed + Select to Edit B. Draw th Draw the products resulting from addition of a Grignard reagent to an aldehyde. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicablelgnore any inorganic byproducts. 1) vinylmagnesium chloride (CH=CHMC) 2) HCI/HO Он Select to Edit C. Draw the major and minor monobromination products of this reaction. D. aw the products of the two step reaction sequence shown below. ash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers. Ignore inorganic byproducts. NBS hv 1. NOCN Edit Major Product Edit the Minor Product 2.HO SOC
5. Complete the following synthesis of the natural product mycophenolic acid. TMSCI OAC pyridine A OAC OH D TosCl pyridine HO. OTMS OTMS OMe Bno heat OH 1. Mg 2. Cô, 3. H,O .COOH Brz FeBra ÓTMS OBn OTMS Meo OBn Мео Na, NH, OH OH H (2 steps) 1. SOCI, G 2. heat HOOC OTMS Meo Meo
Predict the organic products of the reaction. Show stereochemistry clearly.
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