Draw the structure of the principal chemical form(s) that determines pH when the following compounds are dissolved in 1 L water. State whether the pH of the solution is defined by weak acid, weak base, ampholyte, or buffer chemistry. DO NOT CALCULATE pH. a. 0.1 mole H2NCH(CH3)CO2H pK, (CO2H) = 2.34, pKa (NH2) = 9.87 b. 0.05 mole HNO3 and 0.1 mole H2NCH2CH2NH2 pKal = 6.85, pKa2 = 9.93 c. 0.1 mole HSCH2CH2CO2H pKa (CO2H) = 4.34, pK, (SH) = 10.27

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**Instructions for Determining the Principal Chemical Form(s) and pH Characteristics:**

When the following compounds are dissolved in 1 L of water, identify the structure of the principal chemical form(s) that determine the pH. Additionally, specify whether the pH of the solution is governed by weak acid, weak base, ampholyte, or buffer chemistry. Please note that you should not perform pH calculations.

**a. 0.1 mole H₂NCH(CH₃)CO₂H**

   - **pKₐ (CO₂H)** = 2.34
   - **pKₐ (NH₂)** = 9.87

**b. 0.05 mole HNO₃ and 0.1 mole H₂NCH₂CH₂NH₂**

   - **pKₐ₁** = 6.85
   - **pKₐ₂** = 9.93

**c. 0.1 mole HSCH₂CH₂CO₂H**

   - **pKₐ (CO₂H)** = 4.34
   - **pKₐ (SH)** = 10.27

For each case, evaluate the ionizable groups based on the given pKₐ values to determine the predominant species in solution. Consider the nature of the solute (acidic, basic, amphoteric) to classify the chemistry that defines the solution's pH.
Transcribed Image Text:**Instructions for Determining the Principal Chemical Form(s) and pH Characteristics:** When the following compounds are dissolved in 1 L of water, identify the structure of the principal chemical form(s) that determine the pH. Additionally, specify whether the pH of the solution is governed by weak acid, weak base, ampholyte, or buffer chemistry. Please note that you should not perform pH calculations. **a. 0.1 mole H₂NCH(CH₃)CO₂H** - **pKₐ (CO₂H)** = 2.34 - **pKₐ (NH₂)** = 9.87 **b. 0.05 mole HNO₃ and 0.1 mole H₂NCH₂CH₂NH₂** - **pKₐ₁** = 6.85 - **pKₐ₂** = 9.93 **c. 0.1 mole HSCH₂CH₂CO₂H** - **pKₐ (CO₂H)** = 4.34 - **pKₐ (SH)** = 10.27 For each case, evaluate the ionizable groups based on the given pKₐ values to determine the predominant species in solution. Consider the nature of the solute (acidic, basic, amphoteric) to classify the chemistry that defines the solution's pH.
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