Determine the pH of a buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. The Ka for HC,H,O, is 6.3 × 10 Complete Parts 1-3 before submitting your answer. NEXT > The buffer was prepared by dissolving 21.5 g HC,H,O, and 37.7 g of NaC,H,O, in 200.0 mL of solution. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products. HC,H,O (0) H,O(1) H_O(04) CHO (89) Initial (M) Change (M) Equilibrium (M) D 21.5 0.178 0.80 0880-x 1.31x 0.178 + 37.7 OM 0.176 0.201 21.5- 37.7 0.176- RESET 1.31 0.201x Determine the pH of a buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. The Ka for HC,H,O, is 6.3 × 10⁰. Complete Parts 1-3 before submitting your answer. < PREV 2 NEXT > Based on your ICE table (Part 1) and the definition of Ka, set up the expression for Ka in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. 101 10.888) K₂ = (21.5) [37.7] Xx (2x) [1.31+x)(0.178+x)(0.888 + x) 10.176) (21.5.x (0.261) (37.7+ x) = 6.3 x 10° 10.880] [1.31) RESET [0.178] (0.176-x)(0.261 + x) (0.880-x)

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter8: Polyfunctional Acids And Bases
Section: Chapter Questions
Problem 6P
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**Determining the pH of a Buffer Solution**

**Instructions:**

Based on your ICE table (Part 1) and the equilibrium expression for Ka (Part 2), determine the pH of the buffer solution.

**Equation:**

pH = [Input Box]

**Options:**

- 0
- 4.2 × 10⁵
- 6.23
- 4.37
- 2.4 × 10¹¹
- 7.77
- 9.63
- 0.880

**Interface Description:**

- **Navigation Bar:** At the top, there is a progress indicator showing the sequence of parts from 1 to 3. Part 3 is highlighted, indicating the current section.
- **Reset Button:** A red button labeled "RESET" is available for restarting the calculation.

Use the options provided to fill in the pH of the buffer solution.
Transcribed Image Text:**Determining the pH of a Buffer Solution** **Instructions:** Based on your ICE table (Part 1) and the equilibrium expression for Ka (Part 2), determine the pH of the buffer solution. **Equation:** pH = [Input Box] **Options:** - 0 - 4.2 × 10⁵ - 6.23 - 4.37 - 2.4 × 10¹¹ - 7.77 - 9.63 - 0.880 **Interface Description:** - **Navigation Bar:** At the top, there is a progress indicator showing the sequence of parts from 1 to 3. Part 3 is highlighted, indicating the current section. - **Reset Button:** A red button labeled "RESET" is available for restarting the calculation. Use the options provided to fill in the pH of the buffer solution.
### Buffer Solution pH Calculation

To calculate the pH of a buffer solution, we will use an ICE (Initial, Change, Equilibrium) table and the equilibrium constant expression.

#### Problem Setup:
1. **Given:**
    - Weak acid: \( \text{HC}_2\text{H}_3\text{O}_2 \)
    - Dissolved HC\(_2\)H\(_3\)O\(_2\): 21.5 g
    - NaC\(_2\)H\(_3\)O\(_2\) dissolved: 37.7 g
    - Solution volume: 200.0 mL
    - \( K_a \) for HC\(_2\)H\(_3\)O\(_2\) is \( 6.3 \times 10^{-5} \)

2. **ICE Table Setup:**

   | Species        | Initial (M) | Change (M) | Equilibrium (M) |
   |----------------|-------------|------------|------------------|
   | HC\(_2\)H\(_3\)O\(_2\) (aq) |             |                  |                   |
   | H\(^+\) (aq)              |             |                  |                   |
   | C\(_2\)H\(_3\)O\(_2^-\) (aq) |             |                  |                   |

3. **Complete the ICE table to find the equilibrium concentrations of all reactants and products.**

#### Steps:

1. **Determine Initial Concentrations:**
   - Determine the molarity of HC\(_2\)H\(_3\)O\(_2\) and C\(_2\)H\(_3\)O\(_2^-\) using the given masses and solution volume.

2. **Calculate Changes:**
   - Use \(x\) to denote the change in molarity during the reaction.

3. **Find Equilibrium Concentrations:**
   - Apply the changes to find each component's concentration at equilibrium.

#### Equilibrium Expression:

- Based on the ICE table from Part 1 and the definition of \( K_a \):

   \[
   K_a = \frac{[\text{H}^+][\text{C}_2\text{H}_3\text{O}_2^-]}{[\
Transcribed Image Text:### Buffer Solution pH Calculation To calculate the pH of a buffer solution, we will use an ICE (Initial, Change, Equilibrium) table and the equilibrium constant expression. #### Problem Setup: 1. **Given:** - Weak acid: \( \text{HC}_2\text{H}_3\text{O}_2 \) - Dissolved HC\(_2\)H\(_3\)O\(_2\): 21.5 g - NaC\(_2\)H\(_3\)O\(_2\) dissolved: 37.7 g - Solution volume: 200.0 mL - \( K_a \) for HC\(_2\)H\(_3\)O\(_2\) is \( 6.3 \times 10^{-5} \) 2. **ICE Table Setup:** | Species | Initial (M) | Change (M) | Equilibrium (M) | |----------------|-------------|------------|------------------| | HC\(_2\)H\(_3\)O\(_2\) (aq) | | | | | H\(^+\) (aq) | | | | | C\(_2\)H\(_3\)O\(_2^-\) (aq) | | | | 3. **Complete the ICE table to find the equilibrium concentrations of all reactants and products.** #### Steps: 1. **Determine Initial Concentrations:** - Determine the molarity of HC\(_2\)H\(_3\)O\(_2\) and C\(_2\)H\(_3\)O\(_2^-\) using the given masses and solution volume. 2. **Calculate Changes:** - Use \(x\) to denote the change in molarity during the reaction. 3. **Find Equilibrium Concentrations:** - Apply the changes to find each component's concentration at equilibrium. #### Equilibrium Expression: - Based on the ICE table from Part 1 and the definition of \( K_a \): \[ K_a = \frac{[\text{H}^+][\text{C}_2\text{H}_3\text{O}_2^-]}{[\
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