Draw the structure of the major organic product(s) of the reaction. 1. DIBAH, toluene + 2. H30" DIBAH = diisobutylaluminum hydride, [(CH3)2CHCH2]½ÅIH • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.
Draw the structure of the major organic product(s) of the reaction. 1. DIBAH, toluene + 2. H30" DIBAH = diisobutylaluminum hydride, [(CH3)2CHCH2]½ÅIH • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the structure of the major organic product(s) of the reaction.
![**Title: Reaction Mechanism and Product Formation**
**Objective:** Draw the structure of the major organic product(s) of the reaction.
**Reaction Details:**
- **Starting Material:** A compound featuring a phenyl group (benzene ring) connected to an ester group via a two-carbon chain.
- **Reagents:**
1. **DIBAH (Diisobutylaluminum hydride)**, toluene
2. **H₃O⁺**
- **Chemical Equation:**
The structure undergoes reduction with DIBAH followed by hydrolysis with aqueous acid to yield the major organic product.
**DIBAH Details:**
- Full name: Diisobutylaluminum hydride
- Chemical formula: \((\text{CH}_3)_2\text{CHCH}_2]_2\text{AlH}\)
**Instructions:**
- Stereochemistry need not be considered.
- Draw one structure per sketcher. To add additional structures, use the drop-down menu in the bottom right corner.
- Use the ‘+’ sign from the drop-down menu to indicate multiple products if necessary.
**Guidance for Analyzing the Reaction:**
1. **DIBAH Reaction:**
- DIBAH is commonly used for the selective reduction of esters to aldehydes.
2. **Hydrolysis with H₃O⁺:**
- The acid work-up typically helps to neutralize the reaction and adjust the pH for potential further reactions.
Understanding the mechanism and adopting a stepwise approach will assist in drawing the correct structure for the primary organic product of this reaction.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffd872a70-5ce5-4622-ae4a-9dbf686fcff0%2F805f8ee4-66a7-408d-8786-2169e689d708%2Fnzfzz8_processed.png&w=3840&q=75)
Transcribed Image Text:**Title: Reaction Mechanism and Product Formation**
**Objective:** Draw the structure of the major organic product(s) of the reaction.
**Reaction Details:**
- **Starting Material:** A compound featuring a phenyl group (benzene ring) connected to an ester group via a two-carbon chain.
- **Reagents:**
1. **DIBAH (Diisobutylaluminum hydride)**, toluene
2. **H₃O⁺**
- **Chemical Equation:**
The structure undergoes reduction with DIBAH followed by hydrolysis with aqueous acid to yield the major organic product.
**DIBAH Details:**
- Full name: Diisobutylaluminum hydride
- Chemical formula: \((\text{CH}_3)_2\text{CHCH}_2]_2\text{AlH}\)
**Instructions:**
- Stereochemistry need not be considered.
- Draw one structure per sketcher. To add additional structures, use the drop-down menu in the bottom right corner.
- Use the ‘+’ sign from the drop-down menu to indicate multiple products if necessary.
**Guidance for Analyzing the Reaction:**
1. **DIBAH Reaction:**
- DIBAH is commonly used for the selective reduction of esters to aldehydes.
2. **Hydrolysis with H₃O⁺:**
- The acid work-up typically helps to neutralize the reaction and adjust the pH for potential further reactions.
Understanding the mechanism and adopting a stepwise approach will assist in drawing the correct structure for the primary organic product of this reaction.
Transcribed Image Text:**Reaction Problem Description:**
"Draw the structure of the major organic product(s) of the reaction."
**Chemical Reaction:**
- Reactant: A compound containing a cyclopropyl group attached to a nitrogen atom, which is also connected to a carbonyl group (C=O) and an ethyl group.
- Reagents:
1. LiAlH₄ in ether
2. H₂O
**Instructions:**
- You do not have to consider stereochemistry.
- Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
- Separate multiple products using the + sign from the drop-down menu.
**Explanation:**
The diagram depicts a compound with a cyclopropane ring attached to an N-ethyl amide. The reaction involves the use of lithium aluminum hydride (LiAlH₄) as a reducing agent, followed by water (H₂O), to likely reduce the amide to an amine. Cyclopropyl and ethyl groups remain intact as part of the structure.
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