Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the organic product of the Lewis acid-baes reaction shown below. Include all lone pairs and charges as appropriate.
![### Reaction of Tetrahydrofuran with Boron Trifluoride (BF₃)
#### Description:
The image depicts a chemical reaction involving tetrahydrofuran (THF) and boron trifluoride (BF₃).
#### Structure of Reactants:
- **Tetrahydrofuran (THF):** A five-membered ring compound consisting of four carbons and one oxygen atom. The oxygen atom is shown with two lone pairs of electrons, represented by two pairs of dots.
#### Reaction Arrow:
- A vertical arrow points downward, indicating the direction of the reaction when THF reacts with BF₃.
#### Additional Notes:
- **Boron Trifluoride (BF₃):** A compound used typically as a Lewis acid in various chemical reactions. It can form complexes with other compounds like ethers due to its electron-deficient boron atom.
This reaction highlights the use of BF₃ in forming complexes, potentially useful in organic synthesis processes.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F490f2547-0ce5-40bf-bec4-0e2412f216ec%2Ffbba2618-e619-4d50-8bad-d68c685b2abf%2Faq9ph9_processed.png&w=3840&q=75)
Transcribed Image Text:### Reaction of Tetrahydrofuran with Boron Trifluoride (BF₃)
#### Description:
The image depicts a chemical reaction involving tetrahydrofuran (THF) and boron trifluoride (BF₃).
#### Structure of Reactants:
- **Tetrahydrofuran (THF):** A five-membered ring compound consisting of four carbons and one oxygen atom. The oxygen atom is shown with two lone pairs of electrons, represented by two pairs of dots.
#### Reaction Arrow:
- A vertical arrow points downward, indicating the direction of the reaction when THF reacts with BF₃.
#### Additional Notes:
- **Boron Trifluoride (BF₃):** A compound used typically as a Lewis acid in various chemical reactions. It can form complexes with other compounds like ethers due to its electron-deficient boron atom.
This reaction highlights the use of BF₃ in forming complexes, potentially useful in organic synthesis processes.
![### Grignard Reaction with Acetone
This diagram illustrates the reaction between acetone and methyl lithium (CH₃Li).
**Chemical Structures:**
- **Acetone (CH₃COCH₃):** Presented at the top, acetone is depicted with a carbonyl group (C=O) where the carbon atom is double-bonded to an oxygen atom. The oxygen has two lone pairs of electrons, indicated by two dots.
- **CH₃Li (Methyl Lithium):** This reagent is shown as a source of the methyl anion (CH₃⁻).
**Reaction Process:**
An arrow points downward from the acetone to indicate the reaction direction when methyl lithium is used. The addition of CH₃⁻ to the carbonyl group in acetone is a key step in Grignard-type reactions, typically leading to the formation of tertiary alcohols after subsequent steps.
### Key Points:
1. **Reagent:** The CH₃Li acts as a source of CH₃⁻, a strong nucleophile.
2. **Mechanism:** The nucleophilic CH₃⁻ attacks the electrophilic carbon in the carbonyl group of acetone.
This experiment typically involves careful handling under inert conditions due to the reactivity of methyl lithium.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F490f2547-0ce5-40bf-bec4-0e2412f216ec%2Ffbba2618-e619-4d50-8bad-d68c685b2abf%2F0dkn0v_processed.png&w=3840&q=75)
Transcribed Image Text:### Grignard Reaction with Acetone
This diagram illustrates the reaction between acetone and methyl lithium (CH₃Li).
**Chemical Structures:**
- **Acetone (CH₃COCH₃):** Presented at the top, acetone is depicted with a carbonyl group (C=O) where the carbon atom is double-bonded to an oxygen atom. The oxygen has two lone pairs of electrons, indicated by two dots.
- **CH₃Li (Methyl Lithium):** This reagent is shown as a source of the methyl anion (CH₃⁻).
**Reaction Process:**
An arrow points downward from the acetone to indicate the reaction direction when methyl lithium is used. The addition of CH₃⁻ to the carbonyl group in acetone is a key step in Grignard-type reactions, typically leading to the formation of tertiary alcohols after subsequent steps.
### Key Points:
1. **Reagent:** The CH₃Li acts as a source of CH₃⁻, a strong nucleophile.
2. **Mechanism:** The nucleophilic CH₃⁻ attacks the electrophilic carbon in the carbonyl group of acetone.
This experiment typically involves careful handling under inert conditions due to the reactivity of methyl lithium.
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