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Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please!

Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please!

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please!

3,5-Dinitrobenzoates Gently boil 200 mg of 3,5-dinitrobenzoyl chloride and 50 mg of the alcohol for 5 min. Cool the mixture, crush any solid that forms, and add 2 mL of 2% Na2CO3 solution. Continue to grind and stir the solid with the sodium carbonate solution (to remove 3,5-dinitrobenzoic acid) for about a minute, suction filter, and wash the crystals with cold water. Dissolve the product in about 2.5-3 mL of hot ethanol, add water to the cloud point, and allow and allow crystallization to proceed. Wash the 3,5- dinitrobenzoate with water-alcohol and let it dry until next time. NO2 NO₂ BODOH- CHPOTROH + CICO NO₂ RO NO 2
Transcribed Image Text:3,5-Dinitrobenzoates Gently boil 200 mg of 3,5-dinitrobenzoyl chloride and 50 mg of the alcohol for 5 min. Cool the mixture, crush any solid that forms, and add 2 mL of 2% Na2CO3 solution. Continue to grind and stir the solid with the sodium carbonate solution (to remove 3,5-dinitrobenzoic acid) for about a minute, suction filter, and wash the crystals with cold water. Dissolve the product in about 2.5-3 mL of hot ethanol, add water to the cloud point, and allow and allow crystallization to proceed. Wash the 3,5- dinitrobenzoate with water-alcohol and let it dry until next time. NO2 NO₂ BODOH- CHPOTROH + CICO NO₂ RO NO 2
Phenylurethanes Mix 100 mg of anhydrous alcohol and 100 mg of phenyl isocyanate (or a-naphthylurethane), and heat on the water bath for 5 min. Cool, add about 1 mL of ligroin, heat to dissolve the product, perform hot gravity filtration to remove the small amount of diphenylurea (if present), and cool the filtrate in ice, with scratching to induce crystallization. Collect the product by suction filtration and wash the crystals with cold ligroin and let it dry until next time. ROH + O=C=N 0-4 RO N
Transcribed Image Text:Phenylurethanes Mix 100 mg of anhydrous alcohol and 100 mg of phenyl isocyanate (or a-naphthylurethane), and heat on the water bath for 5 min. Cool, add about 1 mL of ligroin, heat to dissolve the product, perform hot gravity filtration to remove the small amount of diphenylurea (if present), and cool the filtrate in ice, with scratching to induce crystallization. Collect the product by suction filtration and wash the crystals with cold ligroin and let it dry until next time. ROH + O=C=N 0-4 RO N
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