What is an appropriate stepwise synthesis for the following synthesis that uses 1-propanol as the only source of carbon and any other reagents as needed? CH3CH2CH2OH CH3CH2CH2CHCOCH2CH2CH3 CH3 O A. 1-propanol reacts with PCC/CH2Cl2 to yield an intermediate that reacts with LDA to yield intermediate X, which has a resonance form Y. 1-propanol also reacts with PCl3 to yield an intermediate Z that reacts with intermediate X, which undergoes the following series of reactions to yield the product: 1. Na2Cr2O7/H2SO4/H2O; 2. Excess CH3CH2CH2OH/H2SO4. OB. 1-propanol reacts with PCC/CH2Cl2, then the product reacts with LDA to produce intermediate X, which has resonance forms. 1-propanol reacts with PCl3, then the product reacts with intermediate X to yield intermediate Y. Intermediate Y reacts with NaBH4/CH3OH to yield the product. SUPPORT OC. 1-propanol reacts with PCl3 to yield intermediate X. 1-propanol also undergoes the following reaction sequence: 1. Na2Cr2O7/H2SO4/H2O; 2. excess CH3CH2CH2OH/H2SO4; 3. LDA; 4. Intermediate X. This yields the product.
What is an appropriate stepwise synthesis for the following synthesis that uses 1-propanol as the only source of carbon and any other reagents as needed? CH3CH2CH2OH CH3CH2CH2CHCOCH2CH2CH3 CH3 O A. 1-propanol reacts with PCC/CH2Cl2 to yield an intermediate that reacts with LDA to yield intermediate X, which has a resonance form Y. 1-propanol also reacts with PCl3 to yield an intermediate Z that reacts with intermediate X, which undergoes the following series of reactions to yield the product: 1. Na2Cr2O7/H2SO4/H2O; 2. Excess CH3CH2CH2OH/H2SO4. OB. 1-propanol reacts with PCC/CH2Cl2, then the product reacts with LDA to produce intermediate X, which has resonance forms. 1-propanol reacts with PCl3, then the product reacts with intermediate X to yield intermediate Y. Intermediate Y reacts with NaBH4/CH3OH to yield the product. SUPPORT OC. 1-propanol reacts with PCl3 to yield intermediate X. 1-propanol also undergoes the following reaction sequence: 1. Na2Cr2O7/H2SO4/H2O; 2. excess CH3CH2CH2OH/H2SO4; 3. LDA; 4. Intermediate X. This yields the product.
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Chapter1: Chemical Foundations
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Question
![What is an appropriate stepwise synthesis for the following synthesis that uses 1-propanol as the only
source of carbon and any other reagents as needed?
CH3CH2CH2OH
CH3CH2CH2CHCOCH2CH2CH3
CH3
O A. 1-propanol reacts with PCC/CH2Cl2 to yield an intermediate that reacts with LDA to
yield intermediate X, which has a resonance form Y. 1-propanol also reacts with PCl3 to
yield an intermediate Z that reacts with intermediate X, which undergoes the following
series of reactions to yield the product: 1. Na2Cr2O7/H2SO4/H2O; 2. Excess
CH3CH2CH2OH/H2SO4.
OB. 1-propanol reacts with PCC/CH2Cl2, then the product reacts with LDA to produce
intermediate X, which has resonance forms. 1-propanol reacts with PCl3, then the product
reacts with intermediate X to yield intermediate Y. Intermediate Y reacts with
NaBH4/CH3OH to yield the product.
SUPPORT
OC. 1-propanol reacts with PCl3 to yield intermediate X. 1-propanol also undergoes the
following reaction sequence: 1. Na2Cr2O7/H2SO4/H2O; 2. excess CH3CH2CH2OH/H2SO4;
3. LDA; 4. Intermediate X. This yields the product.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F83c92fc2-30aa-4a98-8406-0fcd74b41bc2%2F525ba29c-9ba3-475b-abe8-ef9ebd9f002b%2Fiy55axo_processed.png&w=3840&q=75)
Transcribed Image Text:What is an appropriate stepwise synthesis for the following synthesis that uses 1-propanol as the only
source of carbon and any other reagents as needed?
CH3CH2CH2OH
CH3CH2CH2CHCOCH2CH2CH3
CH3
O A. 1-propanol reacts with PCC/CH2Cl2 to yield an intermediate that reacts with LDA to
yield intermediate X, which has a resonance form Y. 1-propanol also reacts with PCl3 to
yield an intermediate Z that reacts with intermediate X, which undergoes the following
series of reactions to yield the product: 1. Na2Cr2O7/H2SO4/H2O; 2. Excess
CH3CH2CH2OH/H2SO4.
OB. 1-propanol reacts with PCC/CH2Cl2, then the product reacts with LDA to produce
intermediate X, which has resonance forms. 1-propanol reacts with PCl3, then the product
reacts with intermediate X to yield intermediate Y. Intermediate Y reacts with
NaBH4/CH3OH to yield the product.
SUPPORT
OC. 1-propanol reacts with PCl3 to yield intermediate X. 1-propanol also undergoes the
following reaction sequence: 1. Na2Cr2O7/H2SO4/H2O; 2. excess CH3CH2CH2OH/H2SO4;
3. LDA; 4. Intermediate X. This yields the product.
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