Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Branch of C(CH3)3 was incorrect.

Transcribed Image Text:**Reaction Overview: Friedel-Crafts Alkylation**
**Objective:**
Draw the major product of the reaction. Ignore inorganic byproducts.
**Starting Material:**
- **Aromatic Ring:** The structure shown is benzene, a six-carbon ring with alternating double bonds.
**Reagents:**
- **(CH₃)₃CCl (1 equiv):** This is tert-butyl chloride, an alkyl halide with three methyl groups attached to a central carbon which is bonded to a chlorine atom.
- **AlCl₃:** Aluminum chloride, a strong Lewis acid used as a catalyst.
**Reaction Details:**
- The reaction involves a Friedel-Crafts alkylation where the aluminum chloride helps to generate a carbocation from tert-butyl chloride. This carbocation then reacts with the benzene ring, adding the tert-butyl group to the ring.
- The most common position for the substitution is the para position if substituents would be involved, but with benzene (which is symmetrical), the product will simply be benzene with a tert-butyl group attached.
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