Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![**Question 14 of 28**
**Task:** Draw the major product of the substitution reaction shown below. Ignore any inorganic byproducts.
**Reaction Details:**
- The starting compound is an organic molecule featuring a three-carbon chain with a bromine (Br) atom attached to the last carbon.
- The reagents provided for the substitution reaction include methanethiol (CH₃SH).
**Instructions:** In the space provided below, draw the major SN1 substitution product that results from the reaction.
[Diagram Area: Dashed box labeled "Draw SN1 Product"]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1fed7a52-65d8-44f4-988f-6c762cda0c09%2F2b8b1df1-60cb-46ff-ac1f-757ccc3aaf23%2Fsw5z0na_processed.jpeg&w=3840&q=75)
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