Draw all the isomers with molecular formula C6H12 that contain a cyclobutane ring. (Hint: There are seven.) Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas.
Carbohydrates
Carbohydrates are the organic compounds that are obtained in foods and living matters in the shape of sugars, cellulose, and starch. The general formula of carbohydrates is Cn(H2O)2. The ratio of H and O present in carbohydrates is identical to water.
Starch
Starch is a polysaccharide carbohydrate that belongs to the category of polysaccharide carbohydrates.
Mutarotation
The rotation of a particular structure of the chiral compound because of the epimerization is called mutarotation. It is the repercussion of the ring chain tautomerism. In terms of glucose, this can be defined as the modification in the equilibrium of the α- and β- glucose anomers upon its dissolution in the solvent water. This process is usually seen in the chemistry of carbohydrates.
L Sugar
A chemical compound that is represented with a molecular formula C6H12O6 is called L-(-) sugar. At the carbon’s 5th position, the hydroxyl group is placed to the compound’s left and therefore the sugar is represented as L(-)-sugar. It is capable of rotating the polarized light’s plane in the direction anticlockwise. L isomers are one of the 2 isomers formed by the configurational stereochemistry of the carbohydrates.
![Problem 4.65
Part A
Draw all the isomers with molecular formula C6H12 that contain a cyclobutane ring. (Hint: There are seven.)
Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate
stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas.
NN
[1]
A"
ΔΙ
H₂C-
H₂C
H 12D EXP. CONT: 10
L
CH₂
d
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H₂C
H₂C
CH₁
CH
H₂C
CH₁
CH
H
C
N
O
S
CI
Br
P
12 of 2
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