Draw a structural formula of the S configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • If a group is achiral, do not use wedged or hashed bonds on it. CH3 CH3 CH;CHCHCN CH;CH,CH,CHCH,CH3 CH2NH2 Draw a structural formula of the RS configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • Ifa group is achiral, do not use wedged or hashed bonds on it. R

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Title: Drawing Stereochemical Structures for Organic Compounds**

**Instructions for Drawing Structural Formulas:**

When drawing the structural formula of the S or RS configuration of an organic compound, follow these guidelines:

1. **Use Wedge/Hash Bonds:**
   - These bonds help indicate the stereochemistry of the molecule. 
   - Wedge bonds represent bonds coming out of the plane towards the viewer.
   - Hash bonds represent bonds going behind the plane away from the viewer.

2. **Including Hydrogen Atoms:**
   - Include hydrogen atoms only at chiral centers for clarity.

3. **Treatment of Achiral Groups:**
   - Do not use wedged or hashed bonds for achiral groups.

**Example Compounds:**

1. **First Compound:**
   - A linear chain with the formula: CH₃CH₂CH₂CH₂CHCH₂CH₃.
   - Side chain branching: CH₃ attached to the main chain, forming a chiral center.
   - Another branch: CH₃CHCN with a terminal NH₂ group.
   - Task: Draw the S configuration using appropriate bonds to reflect chirality.

2. **Second Compound:**
   - A benzene ring structure indicated by a hexagonal cycle.
   - Two chlorines (Cl) are attached to the ring.
   - Chiral centers marked as R and S.
   - Task: Draw the RS configuration showing correct stereochemistry.

**Note:**
Understanding and accurately drawing these configurations is crucial in fields like organic chemistry, where molecular structure influences chemical behavior and interaction.
Transcribed Image Text:**Title: Drawing Stereochemical Structures for Organic Compounds** **Instructions for Drawing Structural Formulas:** When drawing the structural formula of the S or RS configuration of an organic compound, follow these guidelines: 1. **Use Wedge/Hash Bonds:** - These bonds help indicate the stereochemistry of the molecule. - Wedge bonds represent bonds coming out of the plane towards the viewer. - Hash bonds represent bonds going behind the plane away from the viewer. 2. **Including Hydrogen Atoms:** - Include hydrogen atoms only at chiral centers for clarity. 3. **Treatment of Achiral Groups:** - Do not use wedged or hashed bonds for achiral groups. **Example Compounds:** 1. **First Compound:** - A linear chain with the formula: CH₃CH₂CH₂CH₂CHCH₂CH₃. - Side chain branching: CH₃ attached to the main chain, forming a chiral center. - Another branch: CH₃CHCN with a terminal NH₂ group. - Task: Draw the S configuration using appropriate bonds to reflect chirality. 2. **Second Compound:** - A benzene ring structure indicated by a hexagonal cycle. - Two chlorines (Cl) are attached to the ring. - Chiral centers marked as R and S. - Task: Draw the RS configuration showing correct stereochemistry. **Note:** Understanding and accurately drawing these configurations is crucial in fields like organic chemistry, where molecular structure influences chemical behavior and interaction.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY