Draw a structural formula of the S configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • If a group is achiral, do not use wedged or hashed bonds on it. CH3 CH3 CH;CHCHCN CH;CH,CH,CHCH,CH3 CH2NH2 Draw a structural formula of the RS configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • Ifa group is achiral, do not use wedged or hashed bonds on it. R
Draw a structural formula of the S configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • If a group is achiral, do not use wedged or hashed bonds on it. CH3 CH3 CH;CHCHCN CH;CH,CH,CHCH,CH3 CH2NH2 Draw a structural formula of the RS configuration of the compound shown below. • Use the wedge hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. • Ifa group is achiral, do not use wedged or hashed bonds on it. R
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title: Drawing Stereochemical Structures for Organic Compounds**
**Instructions for Drawing Structural Formulas:**
When drawing the structural formula of the S or RS configuration of an organic compound, follow these guidelines:
1. **Use Wedge/Hash Bonds:**
- These bonds help indicate the stereochemistry of the molecule.
- Wedge bonds represent bonds coming out of the plane towards the viewer.
- Hash bonds represent bonds going behind the plane away from the viewer.
2. **Including Hydrogen Atoms:**
- Include hydrogen atoms only at chiral centers for clarity.
3. **Treatment of Achiral Groups:**
- Do not use wedged or hashed bonds for achiral groups.
**Example Compounds:**
1. **First Compound:**
- A linear chain with the formula: CH₃CH₂CH₂CH₂CHCH₂CH₃.
- Side chain branching: CH₃ attached to the main chain, forming a chiral center.
- Another branch: CH₃CHCN with a terminal NH₂ group.
- Task: Draw the S configuration using appropriate bonds to reflect chirality.
2. **Second Compound:**
- A benzene ring structure indicated by a hexagonal cycle.
- Two chlorines (Cl) are attached to the ring.
- Chiral centers marked as R and S.
- Task: Draw the RS configuration showing correct stereochemistry.
**Note:**
Understanding and accurately drawing these configurations is crucial in fields like organic chemistry, where molecular structure influences chemical behavior and interaction.
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