Draw a structural formula for a hydrocarbon with the given molecular formula that undergoes hydroboration-oxidation to give the indicated product. (a) (b) • All hydrogen atoms are implied. • Apply formal charges where appropriate. • Omit lone pairs and radical electrons from your answer. C₂H10 A 1. (sia) BH 2. H₂O₂, NaOH ▾ 88 1. BH₂ CH12 2. HẠO,, NaOH H 10. Salt ChemDoodle LOH
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![**Title: Drawing Structural Formulas for Hydroboration-Oxidation Reactions**
**Introduction:**
In this exercise, you will learn how to draw a structural formula for a hydrocarbon with the specified molecular formula that undergoes a hydroboration-oxidation reaction. The goal is to produce the indicated product.
**Guidelines:**
- All hydrogen atoms are implied.
- Apply formal charges where appropriate.
- Omit lone pairs and radical electrons from your answer.
**Exercise:**
**(a) Reaction 1:**
- Molecular Formula: \( C_7H_{10} \)
- Reagents:
1. \( (sia)_2BH \)
2. \( H_2O_2, NaOH \)
- Product: Cyclopentanecarbaldehyde
**Diagram Tools:**
- The ChemDoodle interface is provided for drawing molecular structures. Various tool icons are available, including those for drawing bonds, rings, and functional groups.
**(b) Reaction 2:**
- Molecular Formula: \( C_7H_{12} \)
- Reagents:
1. \( BH_3 \)
2. \( H_2O_2, NaOH \)
- Product: Cyclopentylmethanol
---
Using these instructions, you will be able to draw the starting hydrocarbon structure that leads to the desired oxidation product through hydroboration-oxidation.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4392dfb6-6634-424e-a711-fd7e2e9bd423%2F5fc1bc6a-c33e-4896-9e5c-6da021b05465%2Fz1ifphz_processed.jpeg&w=3840&q=75)
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