Discuss and analyze the FTIR-spectrum for: Number 1: [Co(NH3)4CO3]NO3

Q: Determine the CFSE in terms of A. and P for the following complexes: W a) [Fe(CN)6]4 b) [Ru(NH3)6]³+…

A: The objective of the question is to determine the Crystal Field Stabilization Energy (CFSE) for the…

Q: Suppose you prepared [Co(en)2Cl2]+. How many isomers, geometric and optical, could be formed?…

A: The complex given is [Co(en)2Cl2]+.

Q: The quantities provided were used for Step 1 in the synthesis of FeC₂O4 • 2 H₂O. (NH₂)₂…

A: #Q.1: The balanced equation for thesynthesis of FeC2O4*2H2O is: (NH4)2[Fe(H2O)6](SO4)2(aq) +…

Q: Which of the following has LFSE O [Cr(H₂0)6]2+ O[Ni(H₂0)6]2+ [Fe(H₂0)6]²+ O[Co(H2O)%]2+ = -40?

A: The term "LFSE" typically stands for "Ligand Field Stabilization Energy." This concept is commonly…

Q: Calculate the crystal field stabilizing energy (CFSE) for the complexes below. [Rh(acac)3],…

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Q: [Ru(H20)6]C12 [Co(NH3)6]Br3 [Co(NH3)5Br]Br2

A: We have to find the coordination number, Oxidation state of central metal atom , charge of the metal…

Q: Is the following reaction endothermic or exothermic? [Co(NH3)5ONO]2+ -> [Co(NH3)5NO2]2+

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Q: Co(OH2)4Cl2] Br  can exhibit both ion-ion isomerism and hydrate isomerism. True OR False

A: Given,  Co(OH2)4Cl2] Br  can exhibit both ion-ion isomerism and hydrate isomerism. The statement is:

Q: The energy of the absorption band in the electronic spectrum of the  [Ti(H2O)6]3+ complex is…

A: Given that [Ti(H2O)6]3+ has more energy of absorption band than [Ti(H2O)4]3+

Q: Give the proper name for the compound [Co(NH3)4]Cl2

A: Given compound :  [Co(NH3)4]Cl2

Q: Draw the MO diagram of ethylenediammine ligand in [Co(en)2cl2] +

A: Ethylenediamine is a bidentate neutral ligand that donates the lone pairs present on N-atoms to form…

Q: The energy of the absorption band in the electronic spectrum of the  [Ti(H2O)6]3+   complex is 20300…

A: Stability of a complex can be explained by CFSE i.e. crystal field stabilisation energy. For this…

Q: How many unpaired electrons does [Cr(OH2)6]2+ have when it has a highspin d electron configuration?

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Q: Explain the differences between cis- and trans- isomers of [Co(en)2Cl2]2SO4.

A: Coordination complexes are made up of metal atoms and ligands. The central metal atom is an electron…

Q: 3. Consider the blue-colored compound, [Cr(H₂O)]3³ and the yellow-colored compound, [Cr(CN)6]³.…

A: The given questions can be explained as:

Q: Which of the following species would have the shortest crystal field splitting? A) [Co(H20),J³* B)…

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Q: Which statement is true regarding the following reaction? cis-Λ-[Co(en)2Cl2]  +  OH−  -->…

A: cis-Λ-[Co(en)2Cl2]+  + OH− --> cis-[Co(en)2Cl…

Q: Indicate how many stereoisomers are possible for each compound. square planar [Pt (NH₂)₂Cl₂]:…

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Q: Assign reason for each of the following :(i) Transition elements exhibit paramagnetic behaviour.(ii)…

A: Interpretation- To assign reason for each of the following-

Q: Does [Co(NH3)4ClBr]+ have an inversion centre?

A: The objective of the question is to determine whether the complex ion Co(NH3)4ClBr+ has an inversion…

Q: Using valence bond theory, explain the following in relation to the complex given below [Cr (CO)6]…

A: VSEPR theory is Valence Shell Electron Pair Repulsion theory.  It helps to find out the…

Q: in which transition are these complexes: 1:[Co(NH3)4CO3]NO3 2:[Co(NH3 )5Cl]Cl2…

A: Co(III) Complexes with Ligands

Q: Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O    3. Does the value of the equilibrium…

A: Equilibrium constant is defined as the ratio of partial pressure of products to the partial pressure…

Q: Which compound do you expect to absorb the highest energy photon? [Co(H2O)6]3+ [Co(NH3)6]3+…

A: In coordination compounds, the more the value of ∆ο, the more the high-energy photon absorbed.…

Q: What is the systematic name for ? {Co(CO)4F2)BR2

A: We have to write the systematic name for of {Co(CO)4F2)Br2

Q: Draw the structures of the stereoisomers possible for [Co(NH3)4Cl2]Cl complex synthesized by Alfred…

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Q: Draw the ground state split d-orbital diagram for  [Co(NH3)6]Cl3

A: We have to draw ground state split d-orbital diagram for [Co(NH3)6]Cl3

Q: Calculate the Co2+ equilibrium concentration when 0.100 mole of [Co(NH3)6](NO3)2 is added to a…

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Q: Coordination Number (explain reasoning  create a model of the cation, and draw its projection…

A: Geometric isomers are two or more coordination compounds which contain the same number and types of…

Q: Classify the isomer below, and give the name of the isomers. [Cr(CO)e][CoCle] and [Co(CO6)][CrCle]

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Q: Why [Co(CN)6]3- is likely to show a Jahn-Teller distortion.

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Q: Draw the complex structure of Co((C6H5)3PO)2(NO3)2

A: The oxidation state of cobalt is +2.

Q: What is the oxidation state and the coordination number of cobalt in [Co(H2O)4CI2]*? O Oxidation…

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Q: Explain the hybrid type and geometric structure of the K3 [Cr (C204) 3] .3H2O complex with VBT.

A: oxidation number of Cr is +3  in this compound .

Q: Which one of the following complexes could be resolved into a pair of optical isomers? (ox = C2O42-)…

A: Optical isomers are two compounds which contain the same number and kinds of atoms, and bonds but…

Q: Does either cis-[Co(en)2Cl2]+ or trans-[Co(en)2Cl2]- have optical isomers?

A: The certain kind of molecules or compounds can rotate the plane of polarised light. They are known…

Q: How many geometrical and/or optical isomers do the following molecules have? Draw a sketch of each…

A: Geometrical isomerism or cis-trans isomerism are isomers having different arrangement of atoms in 3D…

Q: Both [Co(CN)6]3- and [Co(H2O)6]3+ have and octahedral geometry around the metal centers. Applying…

A: Introduction Valence bond theory is a model used to explain the bonding behavior of atoms in…

Q: How many optical and/or geometric isomers does [CoCl2(en)2]+ have?

A: The complex ion [CoCl2(en)2]+:  Dichlorobis(ethylenediamine)cobalt(III) ion, shows optical &…

Q: Identify the color (blue, green, yellow, or orange) for the following Co³+ complexes: [Co(CN)6]³-…

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Q: Which of the following can exhibit cis-trans isomerism? O [Co(H₂O)3C13] _ [Co(NH3)6]3+ _…

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Q: Which two structural features vary between the "deformational" isomers of [Ir2(dimen)4]2+? Group of…

A: To determine the two structural features that vary between the deformational isomers of…

Q: Use the thermodynamic data given below to compute the formation constant, Kf for [Zn(NH3)4]2+ in…

A: Answer:- Firstly a balanced equilibrium equation is written then using given standard enthalpy vqand…

Q: Sketch the MO diagram of Trans- [Co(en)2 C12]CI and Cis-[Co(en)2C12]CI

A: Since the given coordination complexes contain cobalt(III) ions with two ethylenediamine (en)…

Q: [CrCl6]3-has a maximum in its visible absorption spectrum at 735 nm. Calculate its crystal field…

A: The objective of the question is to calculate the crystal field splitting energy for the complex…

Q: Q5 Explain why [FeF.J is colorless whereas [COFJ is colored but exhibits only a single band in the…

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.