Deuterium (D) is an isotope of H. Both D and H have one proton and one electron; H has no neutrons and D has one. Consequently, D and H have nearly identical behavior, but they can be distinguished from each other experimentally due to their different masses. Therefore, replacing an H with a D in a molecule-deuterium isotope labeling-can provide valuable information about a mechanism. With this in mind, how would you synthesize each of the following deuterium-labeled compounds from the analogous unlabeled compound, using D,0 as your only source of deuterium? Hint: You will have to use two separate proton transfer reactions to synthesize each one. (a) (b) (c) OD D.
Deuterium (D) is an isotope of H. Both D and H have one proton and one electron; H has no neutrons and D has one. Consequently, D and H have nearly identical behavior, but they can be distinguished from each other experimentally due to their different masses. Therefore, replacing an H with a D in a molecule-deuterium isotope labeling-can provide valuable information about a mechanism. With this in mind, how would you synthesize each of the following deuterium-labeled compounds from the analogous unlabeled compound, using D,0 as your only source of deuterium? Hint: You will have to use two separate proton transfer reactions to synthesize each one. (a) (b) (c) OD D.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:Deuterium (D) is an isotope of H. Both D and H have one proton and one electron; H has no neutrons and D has one.
Consequently, D and H have nearly identical behavior, but they can be distinguished from each other experimentally
due to their different masses. Therefore, replacing an H with a D in a molecule-deuterium isotope labeling-can
provide valuable information about a mechanism. With this in mind, how would you synthesize each of the following
deuterium-labeled compounds from the analogous unlabeled compound, using D,0 as your only source of deuterium?
Hint: You will have to use two separate proton transfer reactions to synthesize each one.
(a)
(b)
(c)
OD
D.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 2 images

Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY