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Determine the type of the proposed ligand-substitution mechanism for each of the following cases A) Steric crowding slows down the reaction. B) The reactions of [Ni(CO)4] in which phosphines or phosphites replace CO to give [Ni(CO)3L] all occur at the same rate regardless of which phosphine or phosphite is being used. C) The rate constants for formation of [VX(OH2)s] from [V(OH)] and X when X = Ct, NCS, and N3 are in the ratio 1:2:10.

Determine the type of the proposed ligand-substitution mechanism for each of the following cases A) Steric crowding slows down the reaction. B) The reactions of [Ni(CO)4] in which phosphines or phosphites replace CO to give [Ni(CO)3L] all occur at the same rate regardless of which phosphine or phosphite is being used. C) The rate constants for formation of [VX(OH2)s] from [V(OH)] and X when X = Ct, NCS, and N3 are in the ratio 1:2:10.

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Question 81 Determine the type of the proposed ligand-substitution mechanism for each of the following cases A) Steric crowding slows down the reaction. B) The reactions of [Ni(CO),] in which phosphines or phosphites replace CO to give [Ni(CO) L] all occur at the same rate regardless of which phosphine or phosphite is being used. C) The rate constants for formation of [VX(OH₂)s] from [V(OH₂)] and X` when X = Cr, NCS, and N3 are in the ratio 1:2:10.
Transcribed Image Text:Question 81 Determine the type of the proposed ligand-substitution mechanism for each of the following cases A) Steric crowding slows down the reaction. B) The reactions of [Ni(CO),] in which phosphines or phosphites replace CO to give [Ni(CO) L] all occur at the same rate regardless of which phosphine or phosphite is being used. C) The rate constants for formation of [VX(OH₂)s] from [V(OH₂)] and X` when X = Cr, NCS, and N3 are in the ratio 1:2:10.
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