Determine the pH during the titration of 32.5 mL of 0.333 M ethylamine (C₂H5NH2, Kb = 4.3x10-4) by 0.333 M HCIO4 at the following points. (a) Before the addition of any HCIO4| (b) After the addition of 13.5 mL of HCIO4 (c) At the titration midpoint (d) At the equivalence point (e) After adding 49.1 mL of HCIO4

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**Titration of Ethylamine with Perchloric Acid: Calculating pH at Key Points**

This experiment involves determining the pH during the titration of 32.5 mL of 0.333 M ethylamine (C₂H₅NH₂), which has a base dissociation constant (Kb) of 4.3×10⁻⁴, using 0.333 M perchloric acid (HClO₄). The pH is to be calculated at the following key points:

(a) **Before the Addition of Any HClO₄**  
   - Calculate the initial pH of the ethylamine solution.

(b) **After the Addition of 13.5 mL of HClO₄**  
   - Determine the pH after adding the indicated volume of the acid.

(c) **At the Titration Midpoint**  
   - Find the pH at the halfway point to the equivalence.

(d) **At the Equivalence Point**  
   - Calculate the pH when the moles of acid equal the moles of base.

(e) **After Adding 49.1 mL of HClO₄**  
   - Determine the final pH after this amount of acid is added.

**Note**: No graphs or diagrams are present. Solutions require calculations based on stoichiometry and equilibrium chemistry principles.
Transcribed Image Text:**Titration of Ethylamine with Perchloric Acid: Calculating pH at Key Points** This experiment involves determining the pH during the titration of 32.5 mL of 0.333 M ethylamine (C₂H₅NH₂), which has a base dissociation constant (Kb) of 4.3×10⁻⁴, using 0.333 M perchloric acid (HClO₄). The pH is to be calculated at the following key points: (a) **Before the Addition of Any HClO₄** - Calculate the initial pH of the ethylamine solution. (b) **After the Addition of 13.5 mL of HClO₄** - Determine the pH after adding the indicated volume of the acid. (c) **At the Titration Midpoint** - Find the pH at the halfway point to the equivalence. (d) **At the Equivalence Point** - Calculate the pH when the moles of acid equal the moles of base. (e) **After Adding 49.1 mL of HClO₄** - Determine the final pH after this amount of acid is added. **Note**: No graphs or diagrams are present. Solutions require calculations based on stoichiometry and equilibrium chemistry principles.
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