Determine the correct second resonance structure of thioformate ion? 0=c=S–H ..0 O -1 s=c=0-H H. :

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**Question 5 of 15**

**Determine the correct second resonance structure of thioformate ion.**

There are four potential resonance structures presented as options:

1. **Option 1:**
   - Structure: A carbon (C) atom double-bonded to an oxygen (O) atom (O=C). The C is single-bonded to a sulfur (S) atom. 
   - Charge: Oxygen has a charge of 0 and sulfur has a charge of -1.
   - Hydrogen (H) is single-bonded to carbon.

2. **Option 2:**
   - Structure: An oxygen (O) atom double-bonded to a carbon (C) atom (O=C). The C is double-bonded to a sulfur (S) atom (S=C).
   - Charge: Oxygen has a charge of 0 and carbon has a charge of -1.
   - Oxygen has a single lone pair, and sulfur contains two lone pairs.
   - Hydrogen (H) is single-bonded to sulfur. 

3. **Option 3:**
   - Structure: A sulfur (S) atom double-bonded to a carbon (C) atom (S=C). The C is double-bonded to an oxygen (O) atom.
   - Charge: Sulfur has a charge of 0 and oxygen has a charge of -1.
   - Sulfur has a single lone pair, and oxygen contains three lone pairs.
   - Hydrogen (H) is single-bonded to carbon. 

Each structure utilizes Lewis dot structures to depict valence electrons and charges on atoms. Determine the correct one based on formal charges and resonance stability.
Transcribed Image Text:**Question 5 of 15** **Determine the correct second resonance structure of thioformate ion.** There are four potential resonance structures presented as options: 1. **Option 1:** - Structure: A carbon (C) atom double-bonded to an oxygen (O) atom (O=C). The C is single-bonded to a sulfur (S) atom. - Charge: Oxygen has a charge of 0 and sulfur has a charge of -1. - Hydrogen (H) is single-bonded to carbon. 2. **Option 2:** - Structure: An oxygen (O) atom double-bonded to a carbon (C) atom (O=C). The C is double-bonded to a sulfur (S) atom (S=C). - Charge: Oxygen has a charge of 0 and carbon has a charge of -1. - Oxygen has a single lone pair, and sulfur contains two lone pairs. - Hydrogen (H) is single-bonded to sulfur. 3. **Option 3:** - Structure: A sulfur (S) atom double-bonded to a carbon (C) atom (S=C). The C is double-bonded to an oxygen (O) atom. - Charge: Sulfur has a charge of 0 and oxygen has a charge of -1. - Sulfur has a single lone pair, and oxygen contains three lone pairs. - Hydrogen (H) is single-bonded to carbon. Each structure utilizes Lewis dot structures to depict valence electrons and charges on atoms. Determine the correct one based on formal charges and resonance stability.
**Resonance Structures of the Thioformate Ion, HCOS⁻**

The first resonance structure of the thioformate ion, HCOS⁻, is shown below:

- The structure displays a carbon atom (C) bonded to an oxygen atom (O) and a sulfur atom (S). 
- The oxygen has three lone pairs of electrons and carries a negative charge (-1).
- The carbon is bonded to the hydrogen atom (H) and has no lone pairs.
- The sulfur atom has two lone pairs of electrons.

![First Resonance Structure]

**Determine the correct second resonance structure of the thioformate ion from the following options:**

1. **Option 1**:
   - The structure shows carbon bonded to oxygen, carrying three lone pairs, with a double bond (C=O).
   - The carbon is also bonded to sulfur, which has three lone pairs and carries a negative charge (-1).

2. **Option 2**:
   - The structure shows a linear arrangement with oxygen double-bonded to carbon (O=C), which is triple-bonded to sulfur (C≡S).
   - The oxygen has three lone pairs, and the sulfur has one lone pair carrying a negative charge (-1).

3. **Option 3**:
   - The structure shows sulfur double-bonded to carbon (S=C), which is double-bonded to oxygen (C=O).
   - The sulfur has two lone pairs, and the oxygen has three lone pairs with a negative charge (-1).

Analyze these options to find the most stable and correct resonance structure for the thioformate ion based on known principles of resonance and electron distribution.
Transcribed Image Text:**Resonance Structures of the Thioformate Ion, HCOS⁻** The first resonance structure of the thioformate ion, HCOS⁻, is shown below: - The structure displays a carbon atom (C) bonded to an oxygen atom (O) and a sulfur atom (S). - The oxygen has three lone pairs of electrons and carries a negative charge (-1). - The carbon is bonded to the hydrogen atom (H) and has no lone pairs. - The sulfur atom has two lone pairs of electrons. ![First Resonance Structure] **Determine the correct second resonance structure of the thioformate ion from the following options:** 1. **Option 1**: - The structure shows carbon bonded to oxygen, carrying three lone pairs, with a double bond (C=O). - The carbon is also bonded to sulfur, which has three lone pairs and carries a negative charge (-1). 2. **Option 2**: - The structure shows a linear arrangement with oxygen double-bonded to carbon (O=C), which is triple-bonded to sulfur (C≡S). - The oxygen has three lone pairs, and the sulfur has one lone pair carrying a negative charge (-1). 3. **Option 3**: - The structure shows sulfur double-bonded to carbon (S=C), which is double-bonded to oxygen (C=O). - The sulfur has two lone pairs, and the oxygen has three lone pairs with a negative charge (-1). Analyze these options to find the most stable and correct resonance structure for the thioformate ion based on known principles of resonance and electron distribution.
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