Determine the concentration of the titrant in M. Calculate the dissolved oxygen (DO) content of the two water samples in ppm O2.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter19: Principles Of Chemical Reactivity: Electron Transfer Reactions
Section: Chapter Questions
Problem 93GQ
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Read the problem and answer the following questions. Reactions are attached in the picture

Yuno wants to assess the quality of water in the Clover Kingdom and the Heart Kingdom. In order to do this, he took a 200.0 ml sample (T= 20oC)  from the two areas and titrated them with sodium thiosulfate. The water from the Clover Kingdom used up 7.15 ml of the titrant while 7.65 ml where used on the Heart Kingdom’s water. 

Prior to this, 0.1000g of potassium iodate (FM: 214.01 g/mol; 99.97% purity) was weighed and subsequently dissolved in 150.0 ml of distilled water. He took 20.00 ml aliquot of this solution and added 20.00 ml of distilled water. He then treated the solution with potassium iodide and sulfuric acid. Finally, Yuno titrated the solution with 13.7 ml sodium thiosulfate titrant.

  1. Determine the concentration of the titrant in M.
  2. Calculate the dissolved oxygen (DO) content of the two water samples in ppm O2.
A. Standardization of KIO,
B. Dissolved Oxygen Analysis
10, + 81 + 6H → 31, + 3H,O
0,+ 4Mn(ОН), (9 — 4МпО(ОН))+ 2H,0
+ 2H20
25,0 +1, – S,0 + 31
2MNO(OH))
+ 6H* + 21 -→ 2Mn + I, + 4H,0
I + I 215
I +r 215
25,0 +1, – S,0 + 31
I+ starch →I, - starch complex
Transcribed Image Text:A. Standardization of KIO, B. Dissolved Oxygen Analysis 10, + 81 + 6H → 31, + 3H,O 0,+ 4Mn(ОН), (9 — 4МпО(ОН))+ 2H,0 + 2H20 25,0 +1, – S,0 + 31 2MNO(OH)) + 6H* + 21 -→ 2Mn + I, + 4H,0 I + I 215 I +r 215 25,0 +1, – S,0 + 31 I+ starch →I, - starch complex
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