Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:An environmental chemist working for the Environmental Protection Agency (EPA) was directed to collect razor clams from a
heavily-contaminated river superfund site and analyze them for their Cd²+ content using graphite furnace atomic absorption
spectrometry (GFAAS). The chemist dried the clams at 95 °℃ overnight and ground them in a scientific blender, resulting in
approximately 50 g of homogenized dry weight. A representative 73.69 mg sample was taken from the approximately 50 g of
dry material and dissolved in 100.0 mL of 0.1 M HCl to create a sample solution. Using the method of standard additions, the
chemist prepared five standard solutions in 100.0 mL volumetric flasks, each containing 5.00 mL aliquots of the sample
solution. Varying amounts of a 84.0 ppb (µg/L) Cd²+ standard were added to each of the flasks, which were then brought to
volume with 0.1 M HCl. The Cd²+ content of the solutions was then analyzed using GFAAS, resulting in the absorbance data
given in the table.
Sample Volume Cd²+ Standard Volume
(mL)
0.00
2.50
5.00
7.50
10.00
Determine the amount of Cd²+ per gram of dry clam. Express your final result as milligrams of Cd²+ per gram of dry clam.
(mL)
5.00
5.00
5.00
5.00
5.00
Absorbance
0.080
0.119
0.163
0.200
0.241
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