determination of formic acid by neutralization volumetry, an analyst calculated the pH as a function of the addition of NaOH for the titration of 30.00 mL of 0.1280 mol/L formic acid with standardized NaOH with concentration of 0.1570 mol/L. With respect to this titration curve, determine the pH of the solution after adding the following volumes of NaOH: 0.00 mL; 10.00 ml; 25 mL of titrant and at the equivalence point.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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In developing a method for the determination of formic acid by neutralization volumetry, an analyst calculated the pH as a function of the addition of NaOH for the titration of 30.00 mL of 0.1280 mol/L formic acid with standardized NaOH with concentration of 0.1570 mol/L. With respect to this titration curve, determine the pH of the solution after adding the following volumes of NaOH: 0.00 mL; 10.00 ml; 25 mL of titrant and at the equivalence point.

Data: Ka=1.70x10-4. Present the results with two decimal places and show your calculations.

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 pH is a scale used to specify the acidity or basicity of an aqueous solution.

pH is defined as the negativelogarithm of hydrogen ion concentration, i.e. pH = −log [H+] , where [H+] denotes the molar hydrogen ion concentration.

A solution with a pH less than 7 is considered acidic; a solution with a pH greater than 7 is considered basic, or alkaline.

 

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