Describe how the structures of the following can be described in terms of the simple structures types of Table 3.4 but with complex ions: K2PtCl6, [Ni(H2O)][SiF6], CsCN Table 3.4 The crystal structures of compounds, at standard conditions unless otherwise statedCrystal structureExamples*AntifluoriteK,0, K,S, Li,0, Na,0, Na,Se, Na,5Caesium chlorideCSCI, TII (low 7), CSAU, CSCN, Cuzn, NboCaf, UO, HgF, LaH,, Pbo, (high pressure, >6 GPa)NiAs, NIS, FeS, PtSn, CosFluoriteNickel arsenidePerovskiteCaTiO, (distorted), STTIO,, PbZro, LaFe0, LisrH, KMNF;NaCI, KBr, Rbl, AgCI, AgBr, Mg0, Cao, TIO, FeO, NiO, SnAs, UC, ScNTiO (one polymorph), MnO, Sno, WO, MgF, NiF,Rock saltRutileSphalerite (zincblende, cubic)ZnS (one polymorph), CuCI, Cds (Hawleyite polymorph), HgS, CaP, Agl (at high pressure,>6 GPa, transforms to rock salt structure), InA, Zno (high pressure, >6 GPa)MgAI,0, ZnFe,0, ZnCr,S,SpinelWurtzite (hexagonal) Zns (one polymorph), Zno, Be0, Agl (one polymorph, lodargyrite), AIN, SIC, NH,F, Cds(Greenockite polymorph)"A substance in bold type is the one that gives its name to the structure.

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Answered: Describe how the structures of the…

Describe how the structures of the following can be described in terms of the simple structures types of Table 3.4 but with complex ions: K2PtCl6, [Ni(H2O)][SiF6], CsCN

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Describe how the structures of the following can be described in terms of the simple structures types of Table 3.4 but with complex ions: K₂PtCl₆, [Ni(H₂O)][SiF₆], CsCN

Table 3.4 The crystal structures of compounds, at standard conditions unless otherwise stated
Crystal structure
Examples*
Antifluorite
K,0, K,S, Li,0, Na,0, Na,Se, Na,5
Caesium chloride
CSCI, TII (low 7), CSAU, CSCN, Cuzn, Nbo
Caf, UO, HgF, LaH,, Pbo, (high pressure, >6 GPa)
NiAs, NIS, FeS, PtSn, Cos
Fluorite
Nickel arsenide
Perovskite
CaTiO, (distorted), STTIO,, PbZro, LaFe0, LisrH, KMNF;
NaCI, KBr, Rbl, AgCI, AgBr, Mg0, Cao, TIO, FeO, NiO, SnAs, UC, ScN
TiO (one polymorph), MnO, Sno, WO, MgF, NiF,
Rock salt
Rutile
Sphalerite (zinc
blende, cubic)
ZnS (one polymorph), CuCI, Cds (Hawleyite polymorph), HgS, CaP, Agl (at high pressure,
>6 GPa, transforms to rock salt structure), InA, Zno (high pressure, >6 GPa)
MgAI,0, ZnFe,0, ZnCr,S,
Spinel
Wurtzite (hexagonal) Zns (one polymorph), Zno, Be0, Agl (one polymorph, lodargyrite), AIN, SIC, NH,F, Cds
(Greenockite polymorph)
"A substance in bold type is the one that gives its name to the structure.

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