Describe how the structures of the following can be described in terms of the simple structures types of Table 3.4 but with complex ions: K2PtCl6, [Ni(H2O)][SiF6], CsCN

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Describe how the structures of the following can be described in terms of the simple structures types of Table 3.4 but with complex ions: K2PtCl6, [Ni(H2O)][SiF6], CsCN

 

Table 3.4 The crystal structures of compounds, at standard conditions unless otherwise stated
Crystal structure
Examples*
Antifluorite
K,0, K,S, Li,0, Na,0, Na,Se, Na,5
Caesium chloride
CSCI, TII (low 7), CSAU, CSCN, Cuzn, Nbo
Caf, UO, HgF, LaH,, Pbo, (high pressure, >6 GPa)
NiAs, NIS, FeS, PtSn, Cos
Fluorite
Nickel arsenide
Perovskite
CaTiO, (distorted), STTIO,, PbZro, LaFe0, LisrH, KMNF;
NaCI, KBr, Rbl, AgCI, AgBr, Mg0, Cao, TIO, FeO, NiO, SnAs, UC, ScN
TiO (one polymorph), MnO, Sno, WO, MgF, NiF,
Rock salt
Rutile
Sphalerite (zinc
blende, cubic)
ZnS (one polymorph), CuCI, Cds (Hawleyite polymorph), HgS, CaP, Agl (at high pressure,
>6 GPa, transforms to rock salt structure), InA, Zno (high pressure, >6 GPa)
MgAI,0, ZnFe,0, ZnCr,S,
Spinel
Wurtzite (hexagonal) Zns (one polymorph), Zno, Be0, Agl (one polymorph, lodargyrite), AIN, SIC, NH,F, Cds
(Greenockite polymorph)
"A substance in bold type is the one that gives its name to the structure.
Transcribed Image Text:Table 3.4 The crystal structures of compounds, at standard conditions unless otherwise stated Crystal structure Examples* Antifluorite K,0, K,S, Li,0, Na,0, Na,Se, Na,5 Caesium chloride CSCI, TII (low 7), CSAU, CSCN, Cuzn, Nbo Caf, UO, HgF, LaH,, Pbo, (high pressure, >6 GPa) NiAs, NIS, FeS, PtSn, Cos Fluorite Nickel arsenide Perovskite CaTiO, (distorted), STTIO,, PbZro, LaFe0, LisrH, KMNF; NaCI, KBr, Rbl, AgCI, AgBr, Mg0, Cao, TIO, FeO, NiO, SnAs, UC, ScN TiO (one polymorph), MnO, Sno, WO, MgF, NiF, Rock salt Rutile Sphalerite (zinc blende, cubic) ZnS (one polymorph), CuCI, Cds (Hawleyite polymorph), HgS, CaP, Agl (at high pressure, >6 GPa, transforms to rock salt structure), InA, Zno (high pressure, >6 GPa) MgAI,0, ZnFe,0, ZnCr,S, Spinel Wurtzite (hexagonal) Zns (one polymorph), Zno, Be0, Agl (one polymorph, lodargyrite), AIN, SIC, NH,F, Cds (Greenockite polymorph) "A substance in bold type is the one that gives its name to the structure.
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