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- A conduction electron is confined to a metal wire of length (1.46x10^1) cm. By treating the conduction electron as a particle confined to a one-dimensional box of the same length, find the energy spacing between the ground state and the first excited state. Give your answer in eV. Note: Your answer is assumed to be reduced to the highest power possible. Your Answer: x10 Answer(A) for internal energy using the Legendre transform. Show how the Gibbs free energy state function is derived from the state function (B) What are the conditions for G to act as a potential function? (C) Show the mathematical expression for G as a potential function.7. Consider a particle in an infinite square well centered at x = 0 in one of its stationary states. For this problem, you may look up any integrals. Some useful ones are given in Harris. a) Compute (x) and (pr) for arbitrary n. Do this by direct computation but then describe how you could have found these results using symmetry (the symmetry can either be symmetry in the physical system, such as the shape of the wave function, or symmetry related to the expectation value integral, such as the shape of the integrand). b) Using your answer to part a), show that the uncertainty in the momentum is Apx nh for arbitrary n. Do this two ways: (i) first by using your answer to part a) and directly computating (p2) (via an integral) and (ii) by using your answer to part a) and relating (p2) to the kinetic energy operator. c) Show that the uncertainty principle holds for the ground state. 2L -
- what is the difference between a state function and a path function and what are two examples of each?4. a) Consider a square potential well which has an infinite barrier at x = 0 and a barrier of height U at x = L, as shown in the figure. For the case E L) that satisfy the appropriate boundary conditions at x = 0 and x = o. Put the appropriate conditions on x = L to find the allowed energies of the system. Are there conditions for which the solution is not possible? explain. U E L.Consider the sheet formed by the intersection of the curves: x = 0, x = 4, y = 0, y = 3 [=] cm, with a variable density of mass per unit area ρ(x,y) = xy [=] g/cm2 . Write and evaluate multiple integrals to calculate the following: a. The area of the sheet [=] cm2 . b. The mass of the sheet [=] g. c. The shell moments about the x & y axes (Mx & My) [=] g∙cm. d. The position of the center of mass of the sheet ( , ) [=] cm.