Depending on the temperature and pressure, ice can have different types of crystal structure (polymorphic varieties). On Earth, it is in the form of a hexagonal network (called form 1). Between - 70 °C and -140 °C and high pressures it is in the form of a cubic network. At temperatures below -140 °C, it is amorphous (the most common form in the interstellar medium). Water crystallizes in the hexagonal system with the following lattice parameters at 0°C: a = b = 4.523 Å, c = Å7,367; = = 90°; = 120°. 1. From figure 4.1, calculate the volume of the mesh, then the density of water at 0 degree calcius

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Depending on the temperature and pressure, ice can have different types of crystal structure
(polymorphic varieties). On Earth, it is in the form of a hexagonal network (called form I). Between -
70 °C and -140 °C and high pressures it is in the form of a cubic network. At temperatures below -140
°C, it is amorphous (the most common form in the interstellar medium).
Water crystallizes in the hexagonal system with the following lattice parameters at 0°C:
a = b = 4.523 Å, c = Å7,367; = = 90°; = 120°.
1. From figure 4.1, calculate the volume of the mesh, then the density of water at 0 degree
celcius
04
02
03
04
02
03
01
a
Figure: 4.1Representation of the hexagonal mesh of ice. The atomic positions of the oxygen atom in the mesh
are: 01 (1/3; 2/3; 0.0618), 02 (1/3; 2/3; 0.4382), O3 (2/3; 1/3 ;0.5618); 04 (2/3; 1/3 ;0.9382)
8
Transcribed Image Text:Depending on the temperature and pressure, ice can have different types of crystal structure (polymorphic varieties). On Earth, it is in the form of a hexagonal network (called form I). Between - 70 °C and -140 °C and high pressures it is in the form of a cubic network. At temperatures below -140 °C, it is amorphous (the most common form in the interstellar medium). Water crystallizes in the hexagonal system with the following lattice parameters at 0°C: a = b = 4.523 Å, c = Å7,367; = = 90°; = 120°. 1. From figure 4.1, calculate the volume of the mesh, then the density of water at 0 degree celcius 04 02 03 04 02 03 01 a Figure: 4.1Representation of the hexagonal mesh of ice. The atomic positions of the oxygen atom in the mesh are: 01 (1/3; 2/3; 0.0618), 02 (1/3; 2/3; 0.4382), O3 (2/3; 1/3 ;0.5618); 04 (2/3; 1/3 ;0.9382) 8
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