Define Reduction of RCOCl and RCOOR′ with a Metal HydrideReagent ?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Define Reduction of RCOCl and RCOOR′ with a Metal Hydride
Reagent ?

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Step 1

To define the reduction of RCOCl and RCOOR’ with a metal hydride reagent.

Step 2

Metal hydride are the compounds of metal cation and hydride anions. Let consider the a common metal hydride reagent LiAlH4. It act as a strong reducing agent. It reduces the RCOCl (Acyl Chlorides) and RCOOR’ (Esters) to alcohols by the nucleophillic attack of the hydrogen ion of the metal hydride.

The general reaction of the reduction of RCOCl and RCOOR’ is shown below.

RCOClLiAlH4RCH2OHRCOOR'LiAlH4RCH2OH+HOR'

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