CURVED ARROW MECHANISMS FOR ALL i) Bu,SnH, AIBN NC. H AIBN = Me toluene, 110 °C ii) Bu,SnH (1 equiv.) AIBN Toluene, 110 °C iii) TICI,-CaK THF, reflux NH Tip: CK is a strong reducing agent iv) 0.02eq Rh (OAc) N23 N-Boc K CICH,CH;CI 60°C v) 1. NaN, 2. MEOH, reflux vi) ĮMS COTI 2eg CsF M CH,CN, rt

CURVED ARROW MECHANISMS FOR ALL i) Bu,SnH, AIBN NC. H AIBN = Me toluene, 110 °C ii) Bu,SnH (1 equiv.) AIBN Toluene, 110 °C iii) TICI,-CaK THF, reflux NH Tip: CK is a strong reducing agent iv) 0.02eq Rh (OAc) N23 N-Boc K CICH,CH;CI 60°C v) 1. NaN, 2. MEOH, reflux vi) ĮMS COTI 2eg CsF M CH,CN, rt

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

Question

CURVED ARROW MECHANISMS FOR ALL
i)
Bu,SnH, AIBN
NC,
AIBN =
Me
toluene, 110 °C
ii)
Bu, SnH (1 equiv.)
AIBN
Toluene, 110 °C
iii)
TICI,- CaK
THF, reflux
NH
Tip: CK is a strong reducing agent
iv)
0.02eq Rh(OAc)4
N-Boc
K
CICH;CH,CI 60°C
v)
1. NaNg
2. Меон, гefих
vi)
ĮMS
OT
2eg CsF
M
CH,CN, rt

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