Cr3+(aq) → Cr(s) Zn2+(aq) → Zn(s) a. What will be the overall balanced reaction if you want to make a galvanic cell? b. What is the standard cell potential, E°cell?(use values from the provided SRP table) c. If the initial concentrations are [Cr3+]=0.010 M and [Zn2+]=0.0085 M, what is Ecell?

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Cr3+(aq) → Cr(s)
Zn2+(aq) → Zn(s)

a. What will be the overall balanced reaction if you want to make a galvanic cell?

b. What is the standard cell potential, E°cell?(use values from the provided SRP table)

c. If the initial concentrations are [Cr3+]=0.010 M and [Zn2+]=0.0085 M, what is Ecell?

Half-Reaction
E"(V)
F(g) + 2e - 2F (aq)
O,(g) + 2H (aq) + 2e
Co" (ag) + e Co" (aq)
H;O;(aq) + 2H (aq) + 2e 2H;0
PbO;(s) + 4H (aq) + so (aq) + 2e PbSO,(s) + 2H,0
Cet" (ag) + e Ce"(aq)
Mno, (aq) + 8H' (aq) + Se Mn" (aq) + 4H,0
Au" (ag) + 3e Au(s)
Cl(g) + 2e - 2C1 (aq)
CrO (aq) + 14H' (ag) + be - 2Cr" (aq) + 7H;0
MnO;(s) + 4H' (aq) + 2e Mn" (aq) + 2H,0
O,(g) + 4H*(aq) + 4e 2H;0
Br() + 2e - 2Br (aq)
NO, (aq) + 4H' (aq) + 3e
2Hg" (aq) + 2e – Hg" (ag)
Hg" (aq) + 2e 2Hg()
Ag (aq) + e Ag(s)
Fe" (aq) + e
O;(g) + 2H* (aq) + 2e H;O,(aq)
MnO, (aq) + 2H;0 + 3e -
Iz(s) + 2e- 21 (ag)
O,(g) + 2H,0 + 4e 40H (ag)
Cu" (aq) + 2e Cu(s)
* ABCI(s) + e - Ag(s) + CI (aq)
so, (ag) + 4H'(aq) + 2e SO;(g) + 2H;0
Cu" (ag) + e
Sn* (ag) + 2e Sn" (aq)
2H (aq) + 2e"
Pb"
+2.87
+ 0,(8) + H,0
+2.07
+1.82
+1.77
+1.70
+1.61
+1.51
+1.50
+1.36
+1.33
+1.23
+1.23
+1.07
+ NO(g) + 2H;O
+0.96
+0.92
+0.85
+0.80
+0.77
- Fe* (aq)
+0.68
+ MnO,(s) + 4OH (aq)
+0.59
+0.53
+0.40
+0.34
+0.22
+0.20
Cu" (ag)
+0.15
+0.13
H(g)
0.00
(aq) + 2e - Pb(s)
Sn" (ag) + 2e
Ni* (aq) + 2e Ni(s)
Co" (aq) + 2e Co(s)
PbSO,(s) + 2e - Pb(s) + so (ag)
-0.13
Sn(s)
--0.14
-0.25
-0.28
-0.31
Increasing strength as oxidizing agent
Increasing strength as reducing agent
Transcribed Image Text:Half-Reaction E"(V) F(g) + 2e - 2F (aq) O,(g) + 2H (aq) + 2e Co" (ag) + e Co" (aq) H;O;(aq) + 2H (aq) + 2e 2H;0 PbO;(s) + 4H (aq) + so (aq) + 2e PbSO,(s) + 2H,0 Cet" (ag) + e Ce"(aq) Mno, (aq) + 8H' (aq) + Se Mn" (aq) + 4H,0 Au" (ag) + 3e Au(s) Cl(g) + 2e - 2C1 (aq) CrO (aq) + 14H' (ag) + be - 2Cr" (aq) + 7H;0 MnO;(s) + 4H' (aq) + 2e Mn" (aq) + 2H,0 O,(g) + 4H*(aq) + 4e 2H;0 Br() + 2e - 2Br (aq) NO, (aq) + 4H' (aq) + 3e 2Hg" (aq) + 2e – Hg" (ag) Hg" (aq) + 2e 2Hg() Ag (aq) + e Ag(s) Fe" (aq) + e O;(g) + 2H* (aq) + 2e H;O,(aq) MnO, (aq) + 2H;0 + 3e - Iz(s) + 2e- 21 (ag) O,(g) + 2H,0 + 4e 40H (ag) Cu" (aq) + 2e Cu(s) * ABCI(s) + e - Ag(s) + CI (aq) so, (ag) + 4H'(aq) + 2e SO;(g) + 2H;0 Cu" (ag) + e Sn* (ag) + 2e Sn" (aq) 2H (aq) + 2e" Pb" +2.87 + 0,(8) + H,0 +2.07 +1.82 +1.77 +1.70 +1.61 +1.51 +1.50 +1.36 +1.33 +1.23 +1.23 +1.07 + NO(g) + 2H;O +0.96 +0.92 +0.85 +0.80 +0.77 - Fe* (aq) +0.68 + MnO,(s) + 4OH (aq) +0.59 +0.53 +0.40 +0.34 +0.22 +0.20 Cu" (ag) +0.15 +0.13 H(g) 0.00 (aq) + 2e - Pb(s) Sn" (ag) + 2e Ni* (aq) + 2e Ni(s) Co" (aq) + 2e Co(s) PbSO,(s) + 2e - Pb(s) + so (ag) -0.13 Sn(s) --0.14 -0.25 -0.28 -0.31 Increasing strength as oxidizing agent Increasing strength as reducing agent
Co" (aq) + 2e
PbSO,(s) + 2e
Ca* (aq) + 2e
Fe" (aq) + 2e Fe(s)
C*(aq) + 3e Cr(s)
Zn* (aq) + 2e – Zn(s)
2H,0 + 2e H;(g) + 20H (aq)
Mn" (ag) + 2e
Al" (aq) + 3e Al(s)
Be" (aq) + 2e → Be(s)
Mg" (ag) + 2e - Mg(s)
Na (aq) + e
Ca" (aq) + 2e
Sr"(aq) + 2e Sr(s)
Ba"(aq) + 2e – Ba(s)
K'(aq) + e - K(s)
Li' (aq) + e - Li(s)
+ Co(s)
Pb(s) + So, (ag)
Cd(s)
-0.28
-0.31
-0.40
--0.44
-0.74
-0.76
-0.83
+ Mn(s)
-1.18
-1.66
-1.85
-2.37
+ Na(s)
+ Ca(s)
-2.71
-2.87
-2.89
-2.90
-2.93
-3.05
Transcribed Image Text:Co" (aq) + 2e PbSO,(s) + 2e Ca* (aq) + 2e Fe" (aq) + 2e Fe(s) C*(aq) + 3e Cr(s) Zn* (aq) + 2e – Zn(s) 2H,0 + 2e H;(g) + 20H (aq) Mn" (ag) + 2e Al" (aq) + 3e Al(s) Be" (aq) + 2e → Be(s) Mg" (ag) + 2e - Mg(s) Na (aq) + e Ca" (aq) + 2e Sr"(aq) + 2e Sr(s) Ba"(aq) + 2e – Ba(s) K'(aq) + e - K(s) Li' (aq) + e - Li(s) + Co(s) Pb(s) + So, (ag) Cd(s) -0.28 -0.31 -0.40 --0.44 -0.74 -0.76 -0.83 + Mn(s) -1.18 -1.66 -1.85 -2.37 + Na(s) + Ca(s) -2.71 -2.87 -2.89 -2.90 -2.93 -3.05
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