Copper melts at 1083°C. Droplets of liquid Cu had been supercooled to 847°C before isothermal solidification occurred. (a) Calculate entropy change of the system associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (b) Calculate the enthalpy change of the system associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (c) Calculate the entropy change of the surroundings associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (d) Calculate the total entropy change (system and surrounding) for isothermal solidification of supercooled copper at 847°C. Comment on the results. Data At 1083°C, AHL-s = −12958 J/mole Cp (Liquid Cu) = 31.35 J mole.K 3 Cp (Solid Cu) = (22.61 + 6.27 × 10-³T) mole.K

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Chapter17: Chemcial Thermodynamics
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Copper melts at 1083°C. Droplets of liquid Cu had been supercooled to 847°C before isothermal
solidification occurred.
(a) Calculate entropy change of the system associated with the isothermal solidification of 1
mole of supercooled copper at 847°C.
(b) Calculate the enthalpy change of the system associated with the isothermal solidification
of 1 mole of supercooled copper at 847°C.
(c) Calculate the entropy change of the surroundings associated with the isothermal
solidification of 1 mole of supercooled copper at 847°C.
(d) Calculate the total entropy change (system and surrounding) for isothermal solidification
of supercooled copper at 847°C. Comment on the results.
Data
At 1083°C, AHL-s = -12958 J/mole
L→S
Cp (Liquid Cu) = 31.35
J
mole.K
Cp (Solid Cu) = (22.61 + 6.27 × 10−³T)
J
mole.K
Transcribed Image Text:Copper melts at 1083°C. Droplets of liquid Cu had been supercooled to 847°C before isothermal solidification occurred. (a) Calculate entropy change of the system associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (b) Calculate the enthalpy change of the system associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (c) Calculate the entropy change of the surroundings associated with the isothermal solidification of 1 mole of supercooled copper at 847°C. (d) Calculate the total entropy change (system and surrounding) for isothermal solidification of supercooled copper at 847°C. Comment on the results. Data At 1083°C, AHL-s = -12958 J/mole L→S Cp (Liquid Cu) = 31.35 J mole.K Cp (Solid Cu) = (22.61 + 6.27 × 10−³T) J mole.K
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