Consider 0.75 kg of N2 at 300 K, 1 bar contained in a rigid tank connected by a valve to another rigid tank holding 0.3 kg of CO2 at 300 K, 1 bar. The valve is opened and gases are allowed to mix, achieving an equilibrium state at 280 K. Determine: (a) the final pressure, in bar. (b) the magnitude of the heat transfer to or from the gases during the process, in kJ. (c) the entropy change of each gas and of the overall system, in kJ/K.

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Properties of Pure Substances

A substance with fixed chemical composition throughout is called a pure substance like water, air, and nitrogen. A pure substance does not have to be a single element or compound. A mixture of two or more phases of a pure substance is also a pure substance as long as the chemical composition is the same for all phases. These substances mainly have a constant/ uniform composition. The substances also have fixed boiling and melting points. A pure substance takes part in a chemical reaction to form predictable products.